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Flux compression measurements in sintered bulk Ba2YCu3O7

Trapping of magnetic fields and subsequent flux compression have been realized in sintered bulk Ba2YCu3O7 superconductors at 77 K. The field is trapped in two interconnected holes of 0.95-cm and 0.52-cm diameter, respectively. By inserting a superconducting plunger with a diameter of 0.93 cm into the larger hole, the trapped flux is compressed into the smaller hole, where the flux density is measured with a Hall probe. The ratio of the areas available for the magnetic flux before and after compression is 3.7. Deviations from this compression ratio are observed to increase as the trapped field is increased, demonstrating penetration of magnetic flux into the interior of the superconductor. Using a simple extension of the critical state model, the authors demonstrate how the flux compression technique can be used to test the validity of the model and also to calculate the critical current density of the superconductor directly from the measurements.

Israelsson, U. E.↗

Materials Data on Ba2YCu3O7 by Materials Project

YBa2Cu3O7 crystallizes in the orthorhombic Pmmm space group. The structure is three-dimensional. Ba2+ is bonded in a 10-coordinate geometry to ten O2- atoms. There are a spread of Ba–O bond distances ranging from 2.76–3.06 Å. Y3+ is bonded in a body-centered cubic geometry to eight O2- atoms. There are four shorter (2.40 Å) and four longer (2.43 Å) Y–O bond lengths. There are two inequivalent Cu+2.33+ sites. In the first Cu+2.33+ site, Cu+2.33+ is bonded to five O2- atoms to form corner-sharing CuO5 square pyramids. There are a spread of Cu–O bond distances ranging from 1.95–2.30 Å. In the second Cu+2.33+ site, Cu+2.33+ is bonded in a square co-planar geometry to four O2- atoms. There is two shorter (1.88 Å) and two longer (1.96 Å) Cu–O bond length. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded to four equivalent Ba2+ and two equivalent Cu+2.33+ atoms to form a mixture of distorted edge, corner, and face-sharing OBa4Cu2 octahedra. The corner-sharing octahedra tilt angles range from 0–67°. In the second O2- site, O2- is bonded in a 4-coordinate geometry to two equivalent Ba2+, two equivalent Y3+, and two equivalent Cu+2.33+ atoms. In the third O2- site, O2- is bonded in a 4-coordinate geometry to two equivalent Ba2+, two equivalent Y3+, and two equivalent Cu+2.33+ atoms. In the fourth O2- site, O2- is bonded to four equivalent Ba2+ and two Cu+2.33+ atoms to form a mixture of distorted edge, corner, and face-sharing OBa4Cu2 octahedra. The corner-sharing octahedra tilt angles range from 0–67°.

36 MATERIALS SCIENCE↗