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At least 19 records

Hydrogel-assisted self-healing of biomineralized living building materials

Living building materials (LBMs) are an emergent class of structural materials that leverage the biomineralization capability of microorganisms within sand-hydrogel scaffolds to produce living, load-bearing structures. Here we produced LBMs using a physically crosslinkable sand-hydrogel scaffold and two microorganisms with different biomineralization pathways - Synechococcus sp. PCC 7002 (photosynthetic) and S. pasteurii (ureolytic) - and investigated their self-healing capacity. Our results reveal that both Synechococcus sp. PCC 7002 and S. pasteurii demonstrated exceptional viability within all LBMs for more than 20 days. Damaged LBMs containing Synechococcus sp. PCC 7002 exhibited 103% and 112% of their original compressive and flexural strengths, respectively, after three days of healing at 50% relative humidity (RH) (i.e., ambient conditions). In contrast, LBMs containing S. pasteurii exhibited 71% and 66% of their original compressive and flexural strengths, respectively, after three days of healing at 50% RH. The compressive and flexural strengths of all LBMs rebounded to 93-100% after seven days of healing at 50% RH. Data substantiate that the self-healing ability of the hydrogel plays a critical role in facilitating healing of LBMs, as evidenced by the 82-118% rebounds in compressive and flexural strengths by the sand-hydrogel scaffold alone after three or seven days of healing at 50% RH. Healing was less effective at 100% RH for all LBMs investigated herein.

36 MATERIALS SCIENCE↗

Environmentally Friendly Use of Carbon Ore for Advanced Building Materials for Homes and Commercial Buildings

Through this effort, X-MAT CCC sought to confirm the utility and commercialization potential of carbon-derived building materials (CDBM) technology licensed from our partner, Semplastics. These CDBM products contain at least 52% coal-derived carbon by mass. Including the binders within the resin, the products contain at least 71% carbon by mass overall, meeting a key criterion for DE-FOA-0002185 – Area of Interest (AOI) 5 – Design Research and Development, Validation, and Fabrication of a Prototype Carbon-Based Building. The Phase II project has resulted in a technology demonstrator prototype structure, a detailed design for a carbon-based building, and updated techno-economic analysis (TEA) including detailed market surveys to show the commercial viability of CDBM products. We pursued the following objectives in Phase II: (1) construction of a partial building shell as a technology demonstrator, (2) testing of CDBM products, individually and in assemblies, (3) demonstration of bonding of CDBM and traditional building materials (TBM) in structural applications, (4) production of a detailed design for a carbon-based building, and (5) an update of the TEA that was performed in Phase I. In Phase II, X-MAT CCC and our industry team performed the development and testing needed to improve the maturity of the technology from a Technology Readiness Level (TRL) of 5 to TRL 6. CDBM have been shown by our partner Semplastics to exhibit a number of high-performance characteristics, including high strength (five times the flexure strength of the best commercial brick, and more than twice the compressive strength of construction-grade concrete block), lower density, improved mechanical durability and abrasion resistance, very high temperature stability, and resistance to chemicals, acids, salts, and water. These properties offer significant improvements over conventional building materials. Phase II built upon the work accomplished in Phase I by performing technical and economic research and development to confirm the viability of CDBM as commercial products in various markets. Acknowledgment: This material is based upon work supported by the Department of Energy under Award Number DE-FE0031985.

01 COAL, LIGNITE, AND PEAT↗

Certified Green Building Materials: Policy Impact Assessment

Chinese building construction is rapidly expanding, making it critical to focus on energy efficiency to curb the increase of energy consumption and emissions over a building’s lifetime. A key mechanism to do so is through building material certification systems and programs. These establish how building materials will perform and can be used to promote energy and resource efficiency, which help create a more sustainable and healthy building industry. This report begins by identifying characteristics of a strong certification system and ways to improve existing systems. To curb building energy demand, the Chinese government began developing a building material certification program to encourage energy and resource efficiency in the building sector. A timeline is provided of their program’s development and provides analysis. China’s building material database is highlighted and analyzed for their significance and opportunities for improvement. The report then continues to analyze the importance of policies such as procurement programs, and the Chinese government is developing their procurement programs for certified green building materials. To understand the potential large-scale impacts of green building material certifications, we conducted an analysis of the environmental and market impact of a nationwide green building procurement policy for all new residential and commercial construction.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Circular Economy for Building Materials

The building sector is the one of the largest consumers of raw materials and producers of waste in the United States. NREL is working to minimize waste from building construction by conducting research on new materials, construction, and building durability, as well as developing new design principles and modeling tools. These efforts are designed to help transform the "linear economy" - where materials are simply used and disposed - into a circular one.

advanced construction methods↗

Measurements of alpha and beta radiation from uncontaminated surfaces of common building materials using the RadEye SX with Ludlum 43-93 Probe

Federal regulation requires the measurement of radioactivity located in or on potentially-contaminated items or materials prior to public release. Surface radioactivity must be at or below radioactivity limits that are protective of the public. These limits are low enough that contributions to radioactive emissions from naturally occurring radioactive materials (NORM) in the building materials must be considered. In uncontaminated materials, measurements commonly reflect NORM content inside construction materials in addition to radon decay products that have collected on surfaces. Therefore, it is important to quantify typical background NORM count rates to accurately determine the fraction of radioactivity added to building materials by radiological operations.

36 MATERIALS SCIENCE↗

Relative toxicity of pyrolysis products of some building materials

Fourteen samples of building materials were evaluated for relative toxicity using the USF/NASA toxicity screening test method. There appeared to be no major differences in relative toxicity under these conditions between different samples of cellulosic board products and roofing felts.

Hilado, C. J.↗

Sustainable Low-Carbon Building Materials Workshop Report

The virtual Sustainable Low-Carbon Building Materials Workshop, organized and held by the US Department of Energy’s (DOE’s) Oak Ridge National Laboratory (ORNL) on January 25, 2022, focused on identifying the technical barriers to the research, development, and deployment (RD&D) of low-carbon building materials, and on determining what can be done to overcome these technical barriers in the short-, mid-, and long-term future. The meeting brought together key players in the construction chain from industry, academia, and ORNL to promote collaborations that could help meet the goals of accelerating the development and deployment of low-carbon building materials in the United States, and of developing a net-zero (or even negative) carbon neighborhood in the Southeast United States by 2030.

36 MATERIALS SCIENCE↗

A cradle-to-gate based life cycle impact assessment comparing the KBFw EFB hybrid reinforced poly hydroxybutyrate biocomposite and common petroleum-based composites as building materials

Highlights: • Substitute biocomposite with the common petroleum-based composite is proposed. • This substitution declines near 30% in Human Health, Ecosystems, and resources. • Biocomposite as next generation of sustainable & green building materials could be Considered. - Abstract: Aligning the sustainability in construction process can be achieved through material selection process with low impact on environment and human health. Today, biocomposite materials are investigated and developed to replace with none, and less eco-friendly materials used in the construction industry leading to emergence of next generation of sustainable and green building materials. This paper aims to develop a model of fully hybrid bio-based biocomposite based on Life Cycle Assessment (LCA), and comparing it with fully petroleum-based composite, which are common conventional building materials. The methodology framework of this research is determined based on ISO 14040 and 14044. Also, the ReCiPe as the common method in SimaPro software is chosen for appraising and comparing LC impact assessment (LCIA). This research highlights the negative effect of these kinds of building materials with providing single scores coming from three gauges including Human Health, Ecosystems and resources. It is observed that substituting the biocomposite with the fully petroleum-based composite has led to a decline of about 30% in single score outcome. The significance of this research is related to important judgement information to policy makers and the prospective manufacturers in the commercialization phase of this new biocomposites as sustainable and green building materials.

54 ENVIRONMENTAL SCIENCES↗

NORM in Building Materials: A Case Study in Releasing and Disposing of Building Debris within the DOE System - 18123

In 2013, the Office of Management and Budget issued Memorandum 2013-02, clarifying its 'Freeze the Footprint' policy. Memorandum 2013-02 requires that all federal agencies maintain or reduce their total square footage, within each subsequent year, from a FY2012 baseline. Memorandum 2013-02 also requires that total square footage remain constant with respect to the type/intended use of a building. At Los Alamos National Laboratory (LANL), this means that new construction cannot occur without demolition of equivalent (both in type and square footage) building(s). Since 2013, decommissioning and demolition of aging, unused facilities at LANL has increased. In 2016, the TA16-280 building complex was scheduled for demolition. TA16-280 is a former high explosives (HE) processing facility that consists of six buildings connected to each other via weatherproof walkways. It was constructed in the 1950's and has been subsequently used for HE shipping, receiving, and storage. Interviews with radiation protection staff suggest that some of the buildings within the complex may have been used to store depleted uranium metal parts in a non-dispersible form. It is LANL policy to conduct decommissioning surveys for radioactive materials when building history cannot confirm that a structure is radiologically non-impacted. LANL follows the Multi-Agency Radiation Survey and Assessment of Materials and Equipment (MARSAME) process to develop its surveys and clear structures from radiological control. After clearance, a structure may be dispositioned as non-regulated waste, at a significant cost savings compared to regulated disposition pathways such as low-level waste. MARSAME measurements conducted in the 16-280 complex were elevated compared to reference measurements of surrogate materials, and a majority of the survey units failed to pass indistinguishable from background (IFB), which is LANL's unregulated clearance criteria. Further measurements conducted both in situ and in the laboratory indicated the presence of naturally-occurring thorium in several building materials including: poured concrete, the glaze atop ceramic blast tiles, and the porcelain enamel on the exterior of blast-proof ceiling lamps. Other than naturally-occurring thorium, there were no elevated radionuclide concentrations detected in building materials. It should be noted that there was no history of thorium use in the 16-280 complex, and the material in question was in all cases fixed to and within the building materials in question. Except in certain specific cases, such material is exempt from regulation under the Atomic Energy Act of 1954 [3], as amended, and is therefore exempt from regulation under the Nuclear Regulatory Commission, the Department of Energy, and agreement state regulatory frameworks. Despite this regulatory exemption, disposition of material from the 16-280 complex proved to be challenging, principally because local industrial landfills stipulate 'No radioactive material' in their Waste Acceptance Criteria. This disconnect between what is regulated and what is disposable creates a situation where some DOE sites find it easier to disposition property as Low Level Waste in lieu of pursuing a non-regulated disposition pathway. This presentation will explore the specifics of the 16-280 decommissioning project as well as the implications of the release/disposition disconnect for naturally occurring radioactive material and project planning at LANL. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Assessment of natural radioactivity and associated radiation hazards in some building materials used in Kilpenathur, Tiruvannamalai dist, Tamilnadu, India

The present study aimed to measure the radioactivity concentration of naturally occuring radionuclides in the locally used building materials from Kilpenthaur, Tiruvannmalai Dist, Tamilnadu, India. This study will also evaluate the radiation hazard arising due to the use of these materials in the construction of dwellings. The concentrations of natural radionuclides {sup 226}Ra, {sup 232}Th and {sup 40}K in five types of building materials have been measured by gamma spectrometry using NaI (Tl) 3” x 3”detector. The estimated radium equivalent activities (Ra{sub eq}), indoor absorbed gamma dose rate (D{sub R}), annual effective dose rate (H{sub R}) and the external hazard indexes(H{sub ex}) were lower than the recommended safe limit and are comparable with results from similar studies conducted in other countries. Therefore, the use of these building material samples under investigation in the construction of dwellings is considered to be safe for inhabitants.

07 ISOTOPE AND RADIATION SOURCES↗

Ignitability of some insulation and building materials

A variety of insulation and building materials were evaluated for ignitability, using a screening test method developed at the University of San Francisco. Ignitability tended to be greater with the more efficient insulation materials because the insulating qualities resulted in a more rapid rise in temperature at the exposed surface. The use of a noncombustible facing material is recommended to provide protection from surface ignition.

Hilado, C. J.↗

Excessive radon-based radiation in indoor air caused by soil building materials in traditional homes on Đồng Văn karst plateau, northern Vietnam

Radon-based radiation from natural soil building materials is an important factor likely influencing residents’ health as a contributing source of natural radiation. This work aims to quantify the nuclide-specific α-radiation of isotopes 222 Rn and 220 Rn in common types of houses in a region of northern Vietnam, Ɖông Văn karst plateau, to preliminarily (i) evaluate the total annual effective dose rates and (ii) assess the relative risk of cancer induction from indoor α-radiation for inhabitants. The average 222 Rn concentrations in all house types were lower than 100 Bq m -3 , but 220 Rn abundances were far higher than 222 Rn, even up to >1000 Bq m -3 in air close to a wall of unfired-soil bricks. The estimated total annual effective dose rates from indoor 222 Rn and 220 Rn and their progenies to residents with daily exposure of 13 h in the various types of houses range from 3.1 to 4.3 mSv a -1 for houses constructed with modified materials, but up to higher than 6 mSv a -1 in houses with raw building materials. The average risk of developing lung cancer as a consequence of a lifetime exposure to indoor α-radiation in affected homes ranges from 3.9% to 14.6%. 220 Rn and its metallic progenies contribute more than 80% of the total average lung cancer risk from total radon, being responsible for a range of 2.7–14.6% of the risk of developing lung cancer.

54 ENVIRONMENTAL SCIENCES↗

Investigation of photon attenuation coefficient of some building materials used in Turkey

In this study, some building materials regularly used in Turkey, such as concrete, gas concrete, pumice and brick have been investigated in terms of mass attenuation coefficient at different gamma-ray energies. Measurements were carried out by gamma spectrometry containing NaI(Tl) detector. Narrow beam gamma-ray transmission geometry was used for the attenuation measurements. The results are in good agreement with the theoretical calculation of XCOM code.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Lunar building materials: Some considerations on the use of inorganic polymers

The use of inorganic polymer systems synthesized from the available lunar chemical elements, viz., silicon, aluminum, and oxygen to make adhesives, binders, and sealants needed in the fabrication of lunar building materials and the assembly of structures is considered. Inorganic polymer systems, their background, status, and shortcomings, and the use of network polymers as a possible approach to synthesis are examined as well as glassy metals for unusual structural strength, and the use of cold-mold materials as well as foam-sintered lunar silicates for lightweight shielding and structural building materials.

Lee, S. M.↗

Wash Penalty Factors: Insight into the Effects of Water Wash Down of Building Materials for Radionuclide/Nuclear (Rn) Decontamination - 20153

The release of radiological material to the urban environment can have a devastating socio-economic impact. In an urban release scenario, areas around the dispersal epicenter and any areas contaminated via atmospheric deposition may require extensive decontamination. Most recently, our group reported the decontamination efficacy of pressurized water washing of common porous building materials, and compared the penetration depth of the contaminations before and after exposure to pressurized tap water. Here, we continue evaluation of the decontamination efficacy of wash solutions based on potassium (K{sup +}) salt for cesium (Cs), strontium (Sr), and europium (Eu) contaminations on common building surfaces. The surfaces included: the cement used in concrete, the aggregate used in concrete, intact concrete, roadway asphalt, asphalt shingles, and latex paint. We deposited solutions of {sup 137}Cs, {sup 85}Sr, and {sup 152}Eu onto numerous common building materials and exposed these materials to a static bath or low-pressure flow of tap water, 0.1 M potassium chloride (KCl), and 0.5 M KCl. The decontamination efficacy and the depth profile for residual contamination were measured to determine the conditions under which applying a wash solution has benefit compared to physically removing the surface material. To aid in these analyses, we introduced a 'wash penalty factor' to quantify the degree to which contamination migrated into the bulk material by the action of the wash method. On asphalt, 70-80% of the radionuclides were found to be within 0.02 mm of the surface. Cs{sup +} bonded to negative charge sites on the surface of the mineral aggregate (used in concrete) so decontamination was improved by ion exchange with K{sup +}. Sr{sup 2+} is soluble and removed by water, while not bonding to aggregate or demonstrating solubility in the liquid asphalt. Eu{sup 3+} is precipitated and not removed in gentle wash but displays mobility within the pore space that suggests its presence as a colloid. Concrete is more porous than asphalt, and 80% of the radionuclides were within 0.2 mm of the surface for {sup 137}Cs and {sup 152}Eu and 50- 80% for {sup 85}Sr. On concrete, Cs{sup +} bonds similarly to asphalt. Sr{sup 2+} bonds to the cement or precipitates from the alkaline pore water. Eu{sup 3+} sorbs to the cement and then precipitates. In brick, the results for Cs{sup +} and Sr{sup 2+} suggested that diffusion of ions from deeper in the coupon was important. Eu{sup 3+} is removed poorly due to precipitation. We will explain and report example wash penalty factors that vary from 0 to > 1 for the various methods and the implications for deciding when to implement wash down methods. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗