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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS2026

Barium Fluoride as a Standard Reference Material for Infrared Refractometry

This work proposes a standard reference material (SRM) for measurements of refractive index in the infrared spectral region (1–12 μm). The purpose of this material is to enable cross-method comparison of refractive index data obtained through minimum deviation, ellipsometry, interferometry, and prism coupling techniques. This will allow vendors and metrology laboratories, regardless of which technique they employ, to certify that their measurements meet required levels of accuracy, precision, and repeatability. Drawing on foundational work by Tilton at the National Bureau of Standards, a figure of merit for candidate SRM materials is outlined, and three materials are selected for further evaluation. Ultimately, barium fluoride is proposed as the most suitable SRM for the infrared spectral region, based on its broad transmission range, chemical and mechanical stability, low temperature dependence of refractive index, and well-characterized dispersion behavior.

Andrew Howe↗
NASA NTRS2003

Water Atomization of Barium Fluoride: Calcium Fluoride for Enhanced Flow Characteristics of PS304 Feedstock Powder Blend

PS304 is a plasma spray deposited solid lubricant coating with feedstock composed of NiCr, Cr2O3, Ag, and BaF2-CaF2 powders. The effects of rounded BaF2-CaF2 particles on the gravity-fed flow characteristics of PS304 feedstock have been investigated. The BaF2-CaF2 powder was fabricated by water atomization using four sets of process parameters. Each of these powders was then characterized by microscopy and classified by screening to obtain 45 to 106 micron particles and added incrementally from 0 to 10 wt% to the other constituents of the PS304 feedstock, namely nichrome, chromia, and silver powders. The relationship between feedstock flow rate, measured with the Hall flowmeter, and concentration of fluorides was found to be linear in each case. The slopes of the lines were between those of the linear relationships previously reported using angular and spherical fluorides and were closer to the relationship predicted using the rule of mixtures. The results offer a fluoride fabrication technique potentially more cost-effective than gas atomization processes or traditional comminution processes.

Stanford, Malcolm K.↗
NASA NTRS1989

Infrared/submillimeter optical properties data base

The general goal was to build a data base containing optical properties, such as reflectance, transmittance, refractive index, in the far infrared to submillimeter wavelength region. This data base would be limited to selected crystalline materials and temperature between 300 and 2 K. The selected materials were: lithium, lead, and strontium; the bromides of potassium and thallium; the carbides of silicone and tungsten; and the materials of KRS5, KRS6, diamond, and sapphire. Last summer, barium fluoride was selected as prototype material for building the data base. This summer the literature search, preparation of the data for barium fluoride was completed. In addition the literature search for data related to the compounds mentioned was completed. The current status is that barium fluoride is in a form suitable for a NASA internal publication. The papers containing the data on the other materials were xeroxed and they are ready to be reduced. On the reverse side, the top figure is a sample combination of data for the index of refraction at 300 K. The lower figure shows the transmittance vs wavelength at 300 and 80 K. These figures are a sample of many which were developed. Since barium fluoride was studied more than most of the materials listed above, it is clear that additional measurements should be made to fill in the gaps present on both temperature and wavelength data.

Alley, Phillip W.↗
NASA NTRS1984

Zirconium fluoride glass - Surface crystals formed by reaction with water

The hydrated surfaces of a zirconium barium fluoride glass, which has potential for application in optical fibers and other optical elements, were observed by scanning electron microscopy. Crystalline zirconium fluoride was identified by analysis of X-ray diffraction patterns of the surface crystals and found to be the main constituent of the surface material. It was also found that hydrated zirconium fluorides form only in highly acidic fluoride solutions. It is possible that the zirconium fluoride crystals form directly on the glass surface as a result of its depletion of other ions. The solubility of zirconium fluoride is suggested to be probably much lower than that of barium fluoride (0.16 g/100 cu cm at 18 C). Dissolution was determined to be the predominant process in the initial stages of the reaction of the glass with water. Penetration of water into the glass has little effect.

Doremus, R. H.↗
NASA NTRS1987

Self-lubricating coatings for high-temperature applications

Some present-day aeropropulsion systems impose severe demands on the thermal and oxidative stability of lubricant, bearing, and seal materials. These demands will be much more severe for operational systems around the turn of the century. Solid lubricants with maximum temperature capabilities of about 1100 C are known. Unfortunately, none of the solid lubricants with the highest temperature capabilities are effective below approximately 400 C. However, research shows that silver and stable fluorides, such as calcium and barium fluoride act synergistically to provide lubrication from below room temperature to approximately 900 C. Plasma-sprayed, self-lubricating composite coatings that were developed at Lewis are described. Background information is given on coatings, designed as PS100 and PS101, that contain the solid lubricants in a Nichrome matrix. These coatings have low friction coefficients over a wide temperature range, but they have inadequate wear resistance for some long-duration applications. Wear resistance was dramatically improved in a recently developed coating PS200, by replacing the Nichrome matrix material with metal-bonded chromium carbide containing dispersed silver and calcium fluoride/barium fluoride eutectic (CaF2/BaF2). The lubricants control friction and the carbide matrix provides excellent wear resistance. Successful tests of these coatings are discussed.

Sliney, Harold E.↗
NASA NTRS1990

Self-lubricating coatings for high-temperature applications

Solid lubricants with maximum temperature capabilities of about 1100 C are known. Unfortunately, none of the solid lubricants with the highest temperature capabilities are effective below 400 C. However, research at NASA's Lewis Research Center shows that silver and stable fluorides such as calcium and barium fluorides act synergistically to provide lubrication from below room temperature to about 900 C. This paper describes plasma-sprayed composite coatings that contain these solid lubricants in combination with a metal-bonded chromium carbide. The lubricants control friction, and the carbide matrix provides wear resistance. Successful tests of these coatings as backup lubricants for compliant gas bearings in turbomachinery and as self-lubricating liners in a four-cylinder Stirling engine are discussed.

Sliney, Harold E.↗
NASA NTRS1986

1985 Nuclear Science Symposium, 32nd, and 1985 Symposium on Nuclear Power Systems, 17th, San Francisco, CA, October 23-25, 1985, Proceedings

The present conference ranges over topics in high energy physics instrumentation, detectors, nuclear medical applications, health physics and environmental monitoring, reactor instrumentation, nuclear spacecraft instrumentation, the 'Fastbus' data acquisition system, circuits and systems for nuclear research facilities, and the development status of nuclear power systems. Specific attention is given to CCD high precision detectors, a drift chamber preamplifier, a Cerenkov ring imaging detector, novel scintillation glasses and scintillating fibers, a modular multidrift vertex detector, radial wire drift chambers, liquid argon polarimeters, a multianode photomultiplier, the reliability of planar silicon detectors, the design and manufacture of wedge and strip anodes, ultrafast triode photodetectors, photomultiplier tubes, a barium fluoride plastic scintillator, a fine grained neutron hodoscope, the stability of low leakage silicon photodiodes for crystal calorimeters, and X-ray proportional counters. Also considered are positron emission tomography, single photon emission computed tomography, nuclear magnetic resonance imaging, Geiger-Muller detectors, nuclear plant safeguards, a 32-bit Fastbus computer, an advanced light water reactor, and nuclear plant maintenance.

Source record↗
NASA NTRS2016

Laboratory Testing and Performance Verification of the CHARIS Integral Field Spectrograph

The Coronagraphic High Angular Resolution Imaging Spectrograph (CHARIS) is an integral field spectrograph (IFS) that has been built for the Subaru telescope. CHARIS has two imaging modes; the high-resolution mode is R82, R69, and R82 in J, H, and K bands respectively while the low-resolution discovery mode uses a second low-resolution prism with R19 spanning 1.15-2.37 microns (J+H+K bands). The discovery mode is meant to augment the low inner working angle of the Subaru Coronagraphic Extreme Adaptive Optics (SCExAO) adaptive optics system, which feeds CHARIS a coronagraphic image. The goal is to detect and characterize brown dwarfs and hot Jovian planets down to contrasts five orders of magnitude dimmer than their parent star at an inner working angle as low as 80 milliarcseconds. CHARIS constrains spectral crosstalk through several key aspects of the optical design. Additionally, the repeatability of alignment of certain optical components is critical to the calibrations required for the data pipeline. Specifically the relative alignment of the lens let array, prism, and detector must be highly stable and repeatable between imaging modes. We report on the measured repeatability and stability of these mechanisms, measurements of spectral crosstalk in the instrument, and the propagation of these errors through the data pipeline. Another key design feature of CHARIS is the prism, which pairs Barium Fluoride with Ohara L-BBH2 high index glass. The dispersion of the prism is significantly more uniform than other glass choices, and the CHARIS prisms represent the first NIR astronomical instrument that uses L-BBH2as the high index material. This material choice was key to the utility of the discovery mode, so significant efforts were put into cryogenic characterization of the material. The final performance of the prism assemblies in their operating environment is described in detail. The spectrograph is going through final alignment, cryogenic cycling, and is being delivered to the Subaru telescope in April 2016. This paper is a report on the laboratory performance of the spectrograph, and its current status in the commissioning process so that observers will better understand the instrument capabilities. We will also discuss the lessons learned during the testing process and their impact on future high-contrast imaging spectrographs for wavefront control.

Coronagraphic High Angular Resolution Imaging Spec↗
NASA NTRS1985

Effect of chloride incorporation on the crystallization of zirconium-barium-lanthanum-aluminum fluoride glass

One aspect of the influence of preparation procedure on the crystallization behavior of a zirconium-barium-lanthanum-aluminum fluoride glass was studied. The crystallization pattern of this glass may be affected by the chlorine concentration within it. In particular, when such glasses are heated at low temperatures, the alpha-Ba-Zr-F6 crystalline phase forms only in those glasses which contain chloride.

Neilson, G. F.↗