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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Enhancing fatigue life by ductile-transformable multicomponent B2 precipitates in a high-entropy alloy

Catastrophic accidents caused by fatigue failures often occur in engineering structures. Thus, a fundamental understanding of cyclic-deformation and fatigue-failure mechanisms is critical for the development of fatigue-resistant structural materials. Here we report a high-entropy alloy with enhanced fatigue life by ductile-transformable multicomponent B2 precipitates. Its cyclic-deformation mechanisms are revealed by real-time in-situ neutron diffraction, transmission-electron microscopy, crystal-plasticity modeling, and Monte-Carlo simulations. Multiple cyclic-deformation mechanisms, including dislocation slips, precipitation strengthening, deformation twinning, and reversible martensitic phase transformation, are observed in the studied high-entropy alloy. Its improved fatigue performance at low strain amplitudes, i.e., the high fatigue-crack-initiation resistance, is attributed to the high elasticity, plastic deformability, and martensitic transformation of the B2-strengthening phase. This study shows that fatigue-resistant alloys can be developed by incorporating strengthening ductile-transformable multicomponent intermetallic phases.

36 MATERIALS SCIENCE↗
DOE OSTI2014

Asymmetric “melting” and “freezing” kinetics of the magnetostructural phase transition in B2-ordered FeRh epilayers

Synchrotron X-ray diffraction was used to study the phase transformation processes during the magnetostructural transition in a B2-ordered FeRh (001)-oriented epilayer grown on MgO by sputtering. Out-of-plane lattice constant measurements within the hysteretic regime of the transition reveal a microstructure consistent with the coexistence of lattice-expanded and contracted phases in spatially distinct regions. It was found that the phase separation is more pronounced during cooling than heating. Furthermore, whilst lattice-expanded domains that span the height of the film can be undercooled by several kelvins, there is no equivalent superheating. This asymmetry between the cooling and heating processes in FeRh is consistent with the difference in the kinetics of generic freezing and melting transitions.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2013

A SEARCH FOR l-C{sub 3}H{sup +} AND l-C{sub 3}H IN Sgr B2(N), Sgr B2(OH), AND THE DARK CLOUD TMC-1

Pety et al. recently reported the detection of several transitions of an unknown carrier in the Horsehead PDR and attribute them to l-C{sub 3}H{sup +}. Here, we have tested the predictive power of their fit by searching for, and identifying, the previously unobserved J = 1-0 and J = 2-1 transitions of the unknown carrier (B11244) toward Sgr B2(N) in data from the publicly available PRIMOS project. Also presented here are observations of the J = 6-5 and J = 7-6 transitions toward Sgr B2(N) and Sgr B2(OH) using the Barry E. Turner Legacy Survey and results from the Kaifu et al. survey of TMC-1. We calculate an excitation temperature and column density of B11244 of {approx}10 K and {approx}10{sup 13} cm{sup -2} in Sgr B2(N) and {approx}79 K with an upper limit of {<=}1.5 Multiplication-Sign 10{sup 13} cm{sup -2} in Sgr B2(OH) and find trace evidence for the cation's presence in TMC-1. Finally, we present spectra of the neutral species in both Sgr B2(N) and TMC-1, and comment on the robustness of the assignment of the detected signals to l-C{sub 3}H{sup +}.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2017

A Luminous and Isolated Gamma-Ray Flare from the Blazar B2 1215+30

We report that B2 1215+30 is a BL-Lac-type blazar that was first detected at TeV energies by the MAGIC atmospheric Cherenkov telescopes and subsequently confirmed by the Very Energetic Radiation Imaging Telescope Array System (VERITAS) observatory with data collected between 2009 and 2012. In 2014 February 08, VERITAS detected a large-amplitude flare from B2 1215+30 during routine monitoring observations of the blazar 1ES 1218+304, located in the same field of view. The TeV flux reached 2.4 times the Crab Nebula flux with a variability timescale of $\lt 3.6\,\mathrm{hr}$. Multiwavelength observations with Fermi-LAT, Swift, and the Tuorla Observatory revealed a correlated high GeV flux state and no significant optical counterpart to the flare, with a spectral energy distribution where the gamma-ray luminosity exceeds the synchrotron luminosity. Lastly, when interpreted in the framework of a one-zone leptonic model, the observed emission implies a high degree of beaming, with Doppler factor $\delta \gt 10$, and an electron population with spectral index $p\lt 2.3$.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2010

Structure, bonding, and magnetic response in two complex borides: Zr{sub 2}Fe{sub 1-{delta}}Ru{sub 5+{delta}}B2 and Zr{sub 2}Fe{sub 1-{delta}}(Ru{sub 1-x}Rh{sub x}){sub 5+{delta}}B2

Polycrystalline samples of two complex intermetallic borides Zr{sub 2}Fe{sub 1-{delta}}Ru{sub 5+{delta}}B2 and Zr{sub 2}Fe{sub 1-{delta}}(Ru{sub 1-x}Rh{sub x}){sub 5+{delta}}B2 ({delta}=ca. 0.10; x=0.20) were synthesized by high-temperature methods and characterized by single-crystal X-ray diffraction, energy dispersive spectroscopy, and magnetization measurements. Both structures are variants of Sc{sub 2}Fe(Ru{sub 1-x}Rh{sub x}){sub 5}B{sub 2} and crystallize in the space group P4/mbm (no. 127) with the Ti{sub 3}Co{sub 5}B{sub 2}-type structure. These structures contain single-atom, Fe-rich Fe/Ru or Fe/Ru/Rh chains along the c-axis with an interatomic metal-metal distance of 3.078(1) A, a feature which makes them viable for possible low-dimensional temperature-dependent magnetic behavior. Magnetization measurements indicated weak ferrimagnetic ordering with ordering temperatures ca. 230 K for both specimens. Tight-binding electronic structure calculations on a model 'Zr{sub 2}FeRu{sub 5}B{sub 2}' using LDA yielded a narrow peak at the Fermi level assigned to Fe-Fe antibonding interactions along the c-axis, a result that indicates an electronic instability toward ferromagnetic coupling along these chains. Spin-polarized calculations of various magnetic models were examined to identify possible magnetic ordering within and between the single-atom, Fe-rich chains. -- Graphical abstract: Zr{sub 2}FeRu{sub 5-x}Rh{sub x}B{sub 2} (x=0, 1) crystallizes with magnetic atoms forming chains which have been shown to order magnetically depending on the total valence electron count. Magnetic measurements and tight-binding electronic structure calculations are employed to investigate the ordering. Display Omitted

36 MATERIALS SCIENCE↗
DOE OSTI2016

Kinetics of the B1-B2 phase transition in KCl under rapid compression

Kinetics of the B1-B2 phase transition in KCl has been investigated under various compression rates (0.03–13.5 GPa/s) in a dynamic diamond anvil cell using time-resolved x-ray diffraction and fast imaging. Our experimental data show that the volume fraction across the transition generally gives sigmoidal curves as a function of pressure during rapid compression. Based upon classical nucleation and growth theories (Johnson-Mehl-Avrami-Kolmogorov theories), we propose a model that is applicable for studying kinetics for the compression rates studied. The fit of the experimental volume fraction as a function of pressure provides information on effective activation energy and average activation volume at a given compression rate. The resulting parameters are successfully used for interpreting several experimental observables that are compression-rate dependent, such as the transition time, grain size, and over-pressurization. The effective activation energy (Q{sub eff}) is found to decrease linearly with the logarithm of compression rate. When Q{sub eff} is applied to the Arrhenius equation, this relationship can be used to interpret the experimentally observed linear relationship between the logarithm of the transition time and logarithm of the compression rates. The decrease of Q{sub eff} with increasing compression rate results in the decrease of the nucleation rate, which is qualitatively in agreement with the observed change of the grain size with compression rate. The observed over-pressurization is also well explained by the model when an exponential relationship between the average activation volume and the compression rate is assumed.

36 MATERIALS SCIENCE↗
DOE OSTI2013

Procyanidin dimer B2-mediated IRAK-M induction negatively regulates TLR4 signaling in macrophages

Highlights: •Pro B2 elevated the expression of IRAK-M, a negative regulator of TLR signaling. •LPS-induced expression of cell surface molecules was inhibited by Pro B2. •LPS-induced production of pro-inflammatory cytokines was inhibited by Pro B2. •Pro B2 inhibited LPS-induced activation of MAPKs and NF-κB through IRAK-M. •Pro B2 inactivated naïve T cells by inhibiting LPS-induced cytokines via IRAK-M. -- Abstract: Polyphenolic compounds have been found to possess a wide range of physiological activities that may contribute to their beneficial effects against inflammation-related diseases; however, the molecular mechanisms underlying this anti-inflammatory activity are not completely characterized, and many features remain to be elucidated. In this study, we investigated the molecular basis for the down-regulation of toll-like receptor 4 (TLR4) signal transduction by procyanidin dimer B2 (Pro B2) in macrophages. Pro B2 markedly elevated the expression of the interleukin (IL)-1 receptor-associated kinase (IRAK)-M protein, a negative regulator of TLR signaling. Lipopolysaccharide (LPS)-induced expression of cell surface molecules (CD80, CD86, and MHC class I/II) and production of pro-inflammatory cytokines (tumor necrosis factor-α, IL-1β, IL-6, and IL-12p70) were inhibited by Pro B2, and this action was prevented by IRAK-M silencing. In addition, Pro B2-treated macrophages inhibited LPS-induced activation of mitogen-activated protein kinases such as extracellular signal-regulated kinase 1/2, p38, and c-Jun N-terminal kinase and the translocation of nuclear factor κB and p65 through IRAK-M. We also found that Pro B2-treated macrophages inactivated naïve T cells by inhibiting LPS-induced interferon-γ and IL-2 secretion through IRAK-M. These novel findings provide new insights into the understanding of negative regulatory mechanisms of the TLR4 signaling pathway and the immune-pharmacological role of Pro B2 in the immune response against the development and progression of many chronic diseases.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2021

The protective role of Ephrin-B2/EphB4 signaling in osteogenic differentiation under inflammatory environment

Highlights: • Ephrin-B2/EphB4 signaling alleviated the inhibited effect of inflammation on osteogenesis. • The effect of Ephrin-B2/EphB4 signaling might be related to the MAPK pathway. • In vivo application of Ephrin-B2-Fc resulted in less alveolar bone destruction. Inflammation and alveolar bone destruction constitute the main pathological process of periodontitis. However, the molecular mechanisms of bone destruction under the inflammation environment remain unclear. This study aims to explore the role of Ephrin-B2/EphB4 signaling in osteogenic differentiation under the inflammation environment. Mouse pre-osteoblasts MC3T3-E1 were pretreated with lipopolysaccharide of Porphyromonas gingivalis (Pg-LPS). The Ephrin-B2/EphB4 signaling was activated, and the osteogenic differentiation of cells was examined. The results showed that activation of Ephrin-B2/EphB4 signaling promoted the expression levels of osteogenic differentiation-related genes, and also relieved the inhibitory effect of Pg-LPS on osteogenesis. Noticeably, the effect of Ephrin-B2/EphB4 signaling might be related to the mitogen-activated protein kinase (MAPK) pathway. While applying Ephrin-B2-Fc and EphB4-Fc to periodontitis mice, we observed the reduction of alveolar crest destruction. The current study revealed the possible role of Ephrin-B2/EphB4 signaling in reducing bone destruction in periodontitis and suggested its potential values for further research.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2014

Gradient changes in structural condition of the B2 phase of NiTi surface layers after electron-beam treatments

Structural conditions of the B2 phase of the Ti{sub 49.5}Ni{sub 50.5} alloy surface layers before and after electron-beam treatments (pulse duration τ = 150 μs, number of pulses n = 5, beam energy density E ≤ 20 J/cm{sup 2}) were studied by X-ray diffraction analysis. Analysis of the X-ray patterns demonstrates that surface layers modified by electron beam treatment contain phase with B2{sup surf} structure. It is revealed that the lattice parameter of the B2{sup surf} phase in the surface (modified) layer is also higher than the lattice parameter of the B2 phase in the underlying layer (a{sub B2} = 3.0159±0.0005). The values of lattice parameter of phase B2{sup surf} amounted a{sub B2}{sup surf} = 3.0316±0.0005 Å and a{sub B2}{sup surf} = 3.0252±0.0005 Å, for the specimens after electron-beam treatment at E{sub 1} = 15 J/cm{sup 2} and E{sub 2} = 20 J/cm{sup 2}, respectively. Inflated lattice parameters a{sub B2}{sup surf} are associated with changes in the chemical composition and the presence of residual stresses in the surface region of the samples after electron-beam treatments.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2025

Multi-modal characterization of the B2 phase in the Ta-Re binary system

The energy and transportation industries demand materials that retain their mechanical property at high temperatures. Refractory complex concentrated alloys (RCCAs) with a BCC + B2 microstructure offer a potential solution, where maintaining the high temperature mechanical properties can be achieved by precipitation strengthening. This depends on the B2 phase in RCCAs being thermodynamically stable with a high solvus temperature. Recently, we predicted the high temperature stability of the B2 structure in the Ta-Re binary system, using density functional theory. Here, in this study, we provide experimental evidence for the existence of this phase for the first time, using a Ta 65 Re 35 alloy. Despite Ta-Re binary phase diagrams predicting a single-phase BCC microstructure for Ta 65 Re 35 , we show that a high Z nanoscale secondary phase appears after heat treatment at 1550 °C and 1100 °C. Scanning transmission electron microscopy (STEM) revealed that this phase has a cubic structure and is equiatomic TaRe though B2 superlattice reflections were absent in fast Fourier transforms (FFT) and diffraction patterns (DPs). DP simulations indicate that the B2 TaRe superlattice reflections are up to two orders of magnitude weaker than their fundamental reflections, making their detection challenging via electron microscopy. Neutron diffraction confirmed the second phase had a B2 structure. This study identified a previously unobserved high temperature stable B2 phase in the Ta-Re system, enabling the development of new high temperature BCC + B2 RCCAs.

36 MATERIALS SCIENCE↗
DOE OSTI2018

B2 Grain Growth Behavior of a Ti-22Al-25Nb Alloy Fabricated by Hot Pressing Sintering

Grain growth behavior of a powder metallurgy (P/M) Ti-22Al-25Nb alloy was investigated by applying a series of isothermal treatment tests over a wide range of temperatures and holding times. An isothermal treatment scheme was conducted in the B2 phase region (1070-1110 °C) and α{sub 2} + B2 phase region (1010-1050 °C) at holding times of 10, 30 min, 1, 2, and 3 h, respectively. The effects of temperature and holding time on the microstructure evolution and microhardness of the P/M Ti-22Al-25Nb alloy at elevated temperatures were evaluated using optical microscope, scanning electron microscope, x-ray diffraction, and Vickers hardness test techniques. The results revealed that the alloy’s treated microstructure was closely linked to temperature and holding time, respectively. The change law of B2 grain growth with holding time and temperature can be well interpreted by the Beck equation and Hillert equation, respectively. The B2 grain growth exponent n and activation energy Q were acquired based on experimental data in the α{sub 2} + B2 and B2 phase regions. In addition, the grain growth contour map for the P/M Ti-22Al-25Nb alloy was constructed to depict variations in B2 grain size based on holding time and temperature.

36 MATERIALS SCIENCE↗
DOE OSTI2015

Hard X-ray morphological and spectral studies of the galactic center molecular cloud SGR B2: Constraining past SGR A{sup ⋆} flaring activity

In 2013, NuSTAR observed the Sgr B2 region and for the first time resolved its hard X-ray emission on subarcminute scales. Two prominent features are detected above 10 keV: a newly emerging cloud, G0.66−0.13, and the central 90″ radius region containing two compact cores, Sgr B2(M) and Sgr B2(N), surrounded by diffuse emission. It is inconclusive whether the remaining level of Sgr B2 emission is still decreasing or has reached a constant background level. A decreasing X-ray emission can be best explained by the X-ray reflection nebula scenario, where the cloud reprocesses a past giant outburst from Sgr A{sup ⋆}. In the X-ray reflection nebula (XRN) scenario, the 3–79 keV Sgr B2 spectrum allows us to self-consistently test the XRN model using both the Fe Kα line and the continuum emission. The peak luminosity of the past Sgr A{sup ⋆} outburst is constrained to L{sub 3−79keV}∼5×10{sup 38} erg s{sup −1}. A newly discovered cloud feature, G0.66−0.13, shows different timing variability. We suggest that it could be a molecular clump located in the Sgr B2 envelope reflecting the same Sgr A{sup ⋆} outburst. In contrast, if the Sgr B2 X-ray emission has reached a constant background level, it would imply an origin of low-energy cosmic-ray (CR) proton bombardment. In this scenario, from the NuSTAR measurements we infer a CR ion power of dW/dt=(1−4)×10{sup 39} erg s{sup −1} and a CR ionization rate of ζ{sub H}=(6−10)×10{sup −15} H{sup −1} s{sup −1}. These measurements can become powerful tools to constrain the GC CR population.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2020

Phase Inversion in a Two-phase, BCC+B2, Refractory High Entropy Alloy

A phenomenon of "phase inversion", presumably the first ever experimental evidence in metallic alloys, is shown in a refractory high entropy alloy (RHEA), Al0.5NbTa0.8Ti1.5V0.2Zr. Phase inversion in crystalline solid systems is driven by the differences in elastic modulus of the two phases. Quenching from a high-temperature single phase field, the RHEA exhibits a co-continuous mixture of a disordered BCC and an ordered B2 phase, that upon isothermal annealing at 600°C develops via spinodal decomposition into a continuous B2 matrix with discrete cuboidal BCC precipitates aligned along the <001> directions. Longer term annealing at 600°C results in the development of necking constrictions along the B2 channels, eventually pinching-off these channels and making the BCC phase continuous with discrete B2 precipitates. This inversion the process can be related to the simultaneous operation of two processes:(i) spheroidization of the initially discrete cuboidal BCC precipitates driven by a reduction in the total interface energy and (ii) an increase in the stiffness of the B2 phase, relative to the BCC phase, due to chemical composition changes during annealing, forcing the B2 regions to become discrete driven by the reduction in the total elastic strain energy.

Soni, Vishal↗
DOE OSTI2018

Observation of a new B2 structured phase in Ti-15Mo (wt%)

Highlights: • Ti-15Mo (wt%) studied in TEM during in situ heat treatment at 300 °C. • Initial microstructure (beta and athermal omega) evolved during exposure. • New B2 phase observed during heat treatment of electron transparent material. • B2 phase formed in regular arrays of square cross-section particles. • B2 phase lattice parameter smaller than beta phase resulting in misfit strain - Abstract: The formation of non-equilibrium and transient phases in metastable beta titanium alloys during low temperature thermal treatments is currently of great interest, as they provide a potential method of controlling the size and distribution of the equilibrium alpha phase and, hence, the resulting mechanical properties. Here, for the first time, we report on the formation of a new, B2 structured phase in the Ti-Mo system. The phase was observed in electron transparent material during in situ, and following ex situ, heat treatment at 300 °C. The B2 phase was enriched in Mo compared to the surrounding matrix material and formed in regular arrays of approximately square cross-section particles interspersed by thin beta channels. Electron diffraction indicated that the lattice parameter of this new phase was smaller than that of the parent phase, leading to significant strain in the beta channels. Critically, the B2 phase was only observed in material that had been electro-polished prior to heat treatment, and, therefore, it is hypothesised that this phase forms as a result of the preparation method and thin foil effects.

36 MATERIALS SCIENCE↗
DOE OSTI2015

In-situ X-ray diffraction studies of the phase transformations and structural states of B2, R and B19′ phases in Ti{sub 49.5}Ni{sub 50.5} alloy

The martensitic transformation, Debye–Waller factor, mean-square atomic displacements and the coefficient of thermal expansion on cooling of the Ti{sub 49.5}Ni{sub 50.5} shape memory alloy were examined using in-situ X-ray diffraction. It was revealed B2→R (T{sub R} ≡ T = 273 ± 10 K) along with B2→B19’ (M{sub s} ≡ T = 273 ± 10 K) transitions occur. It was found that Debye–Waller factor and mean-square displacement of B2 phase undergo significant increase as functions of temperature when phase transition B2→R and B2→B19’ take place. The analysis of the thermal expansion coefficient of the B2 phase indicates that the value of a increases almost linearly while cooling.

36 MATERIALS SCIENCE↗
DOE OSTI2010

OBSERVATIONS OF THE [HNCS]/[HSCN] RATIO IN Sgr B2 AND TMC-1: EVIDENCE FOR LOW-TEMPERATURE GAS-PHASE CHEMISTRY

Millimeter observations of isothiocyanic acid (HNCS) and its higher energy isomer, thiocyanic acid (HSCN), have been carried out toward Sgr B2 and TMC-1 using the 12 m telescope of the Arizona Radio Observatory. For both species, the J{sub Ka,Kc} = 8{sub 0,8} {yields} 7{sub 0,7} and 9{sub 0,9} {yields} 8{sub 0,8} transitions near 91-93 GHz and 103-106 GHz were mapped across a 6' x 3' region, centered near Sgr B2(M). Comparative mapping observations were also done for the J{sub Ka,Kc} = 4{sub 0,4} {yields} 3{sub 0,3} line of HNCO and HOCN near 84-87 GHz. In addition, the J{sub Ka,Kc} = 7{sub 0,7} {yields} 6{sub 0,6} and 8{sub 0,8} {yields} 7{sub 0,7} transitions of both HNCS and HSCN were detected in TMC-1, the first identification of either molecule in a cold, dark cloud. Emission from HNCS and HSCN was found to be extended over the Sgr B2 cloud, with a single velocity component and a linewidth of {approx}20-25 km s{sup -1}. Column densities derived for HSCN in Sgr B2 are typically N{sub tot} {approx} (0.2-1) x 10{sup 13} cm{sup -2}, with N{sub tot} {approx} (0.8-5) x 10{sup 13} cm{sup -2} for the more stable isomer, HNCS. In TMC-1, these species have similar column densities of (6-8) x 10{sup 10} cm{sup -2}. The [HNCS]/[HSCN] abundance ratio ranges from 2 to 7 in Sgr B2, with a value of {approx}1 in TMC-1. In contrast, the [HNCO]/[HOCN] ratio in Sgr B2 is {approx}110-250. Gas-grain chemical models do not reproduce the observed abundances of the sulfur isomers in either source. Given the energy difference of over 3200 K between HNCS and HSCN, these observations suggest that both molecules are produced from gas-phase, ion-molecule chemistry with a common precursor, HNCSH{sup +}. The oxygen analogs, in contrast, probably have a more complex chemical network, perhaps involving the H{sub 2}NCO{sup +} precursor, which preferentially leads to HNCO.

79 ASTRONOMY AND ASTROPHYSICS↗