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Sn-InAs Nanowire Shadow-Defined Josephson Junctions

Hybrid superconductor–semiconductor platforms are foundational to advancing quantum information technologies, motivating the integration of materials with clean interfaces, robust superconductivity, and scalable architectures. Here, in this work, we report the synthesis and analysis of inclined InAs nanowires, conformally coated with β-Sn shells. These nanowires extend in opposite in-plane directions, forming a self-aligned, criss-cross network. This enables the deterministic formation of nanowire-shadow Josephson junctions through angle-controlled, low-temperature Sn deposition. Structural characterization shows uniform polycrystalline β-Sn shells forming a sharp, diffusion-free interface with InAs. Low-temperature transport measurements reveal a hard induced superconducting gap ≈ 600 μeV, switching currents up to ≈ 500 nA, and parallel magnetic field resilience beyond 1T. These results establish β-Sn/InAs nanowire networks as a promising platform for superconducting qubits, low-noise microwave devices, and the exploration of exotic superconducting phases including triplet pairing and topological superconductivity.

B-Sn↗

Transmon Qubit Using Sn as a Junction Superconductor

Superconductor qubits typically use aluminum–aluminum oxide tunnel junctions to provide the nonlinear inductance. Junctions with semiconductor barriers make it possible to vary the superconductor material and explore beyond aluminum. We use InAs semiconductor nanowires coated with thin superconducting shells of β-Sn to realize transmon qubits. By tuning the Josephson energy with a gate voltage, we adjust the qubit frequency over a range of 3 GHz. The longest energy relaxation time, T 1 = 27 μs, is obtained at the lowest qubit frequencies, while the longest echo dephasing time, T 2 = 1.8 μs, is achieved at higher frequencies. Finally, we assess the possible factors limiting coherence times in these devices and discuss steps to enhance performance through improvements in materials fabrication and circuit design.

B-Sn↗

Materials Data on Sn3B by Materials Project

B(Sn)3 is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional and consists of one boron molecule and one Sn framework. In the Sn framework, Sn is bonded in a 8-coordinate geometry to eight equivalent Sn atoms. All Sn–Sn bond lengths are 3.20 Å.

36 MATERIALS SCIENCE↗

Materials Data on SnB by Materials Project

BSn is Wurtzite structured and crystallizes in the hexagonal P6_3mc space group. The structure is three-dimensional. B3- is bonded to four equivalent Sn3+ atoms to form corner-sharing BSn4 tetrahedra. There are one shorter (2.27 Å) and three longer (2.32 Å) B–Sn bond lengths. Sn3+ is bonded to four equivalent B3- atoms to form corner-sharing SnB4 tetrahedra.

36 MATERIALS SCIENCE↗

Materials Data on Sn3B by Materials Project

B(Sn)3 is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional and consists of four boron, metallic molecules and one Sn framework. In the Sn framework, there are two inequivalent Sn sites. In the first Sn site, Sn is bonded to four equivalent Sn atoms to form a mixture of edge and corner-sharing SnSn4 tetrahedra. All Sn–Sn bond lengths are 3.11 Å. In the second Sn site, Sn is bonded in a body-centered cubic geometry to eight equivalent Sn atoms.

36 MATERIALS SCIENCE↗

Materials Data on SnB6 by Materials Project

(B)6Sn is Calcium hexaboride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional and consists of one tin powder molecule and one B framework. In the B framework, B is bonded in a 5-coordinate geometry to five equivalent B atoms. There is one shorter (1.70 Å) and four longer (1.77 Å) B–B bond length.

36 MATERIALS SCIENCE↗

Materials Data on Sn3B by Materials Project

B(Sn)3 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional and consists of two boron molecules and one Sn framework. In the Sn framework, there are two inequivalent Sn sites. In the first Sn site, Sn is bonded in a 8-coordinate geometry to eight Sn atoms. There are four shorter (3.16 Å) and four longer (3.24 Å) Sn–Sn bond lengths. In the second Sn site, Sn is bonded in a 8-coordinate geometry to eight equivalent Sn atoms.

36 MATERIALS SCIENCE↗