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Materials Data on BPt by Materials Project
PtB crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. Pt is bonded in a 6-coordinate geometry to six equivalent B atoms. All Pt–B bond lengths are 2.36 Å. B is bonded in a body-centered cubic geometry to six equivalent Pt and two equivalent B atoms. Both B–B bond lengths are 1.83 Å.
Materials Data on BPt3 by Materials Project
Pt3B crystallizes in the hexagonal P6_3/mmc space group. The structure is one-dimensional and consists of two Pt3B ribbons oriented in the (0, 0, 1) direction. Pt is bonded in a distorted L-shaped geometry to two equivalent B atoms. Both Pt–B bond lengths are 2.18 Å. B is bonded to six equivalent Pt atoms to form distorted face-sharing BPt6 pentagonal pyramids.
Materials Data on BPt by Materials Project
PtB is Caswellsilverite-derived structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. Pt is bonded to six equivalent B atoms to form a mixture of edge, face, and corner-sharing PtB6 octahedra. The corner-sharing octahedral tilt angles are 48°. All Pt–B bond lengths are 2.28 Å. B is bonded to six equivalent Pt atoms to form a mixture of distorted edge and corner-sharing BPt6 pentagonal pyramids.