Materials Data on BMoW by Materials Project
WMoB crystallizes in the orthorhombic Fmmm space group. The structure is three-dimensional. W is bonded in a 4-coordinate geometry to eight equivalent Mo and four equivalent B atoms. There are a spread of W–Mo bond distances ranging from 2.92–3.04 Å. All W–B bond lengths are 2.39 Å. Mo is bonded in a 4-coordinate geometry to eight equivalent W, three equivalent Mo, and four equivalent B atoms. There are one shorter (2.66 Å) and two longer (2.70 Å) Mo–Mo bond lengths. All Mo–B bond lengths are 2.40 Å. B is bonded in a 10-coordinate geometry to four equivalent W and four equivalent Mo atoms.
36 MATERIALS SCIENCE↗