Results for “B-F-Tl”

Materials Data on TlBF4 by Materials Project

TlBF4 is Iron carbide-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Tl1+ is bonded in a 12-coordinate geometry to ten F1- atoms. There are a spread of Tl–F bond distances ranging from 2.97–3.27 Å. B3+ is bonded in a tetrahedral geometry to four F1- atoms. There are a spread of B–F bond distances ranging from 1.41–1.43 Å. There are three inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to three equivalent Tl1+ and one B3+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to three equivalent Tl1+ and one B3+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one Tl1+ and one B3+ atom.