Materials Data on AuO2F by Materials Project
AuO2F crystallizes in the orthorhombic C222_1 space group. The structure is two-dimensional and consists of two AuO2F sheets oriented in the (0, 1, 0) direction. Au5+ is bonded in a square co-planar geometry to two equivalent O2- and two equivalent F1- atoms. Both Au–O bond lengths are 2.05 Å. Both Au–F bond lengths are 2.13 Å. O2- is bonded in a distorted bent 120 degrees geometry to one Au5+ and one O2- atom. The O–O bond length is 1.32 Å. F1- is bonded in a bent 120 degrees geometry to two equivalent Au5+ atoms.
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