SEARCH · Engineering Papers
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
AuClO2 crystallizes in the monoclinic P2_1/m space group. The structure is one-dimensional and consists of two hydrogen peroxide molecules and two AuCl ribbons oriented in the (0, 1, 0) direction. In each AuCl ribbon, Au5+ is bonded in an L-shaped geometry to two equivalent Cl1- atoms. Both Au–Cl bond lengths are 2.42 Å. Cl1- is bonded in an L-shaped geometry to two equivalent Au5+ atoms.
AuO2Cl crystallizes in the orthorhombic C222_1 space group. The structure is two-dimensional and consists of two AuO2Cl sheets oriented in the (0, 1, 0) direction. Au5+ is bonded in a rectangular see-saw-like geometry to two equivalent O2- and two equivalent Cl1- atoms. Both Au–O bond lengths are 2.09 Å. Both Au–Cl bond lengths are 2.44 Å. O2- is bonded in a distorted bent 120 degrees geometry to one Au5+ and one O2- atom. The O–O bond length is 1.32 Å. Cl1- is bonded in a distorted water-like geometry to two equivalent Au5+ atoms.