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Zr2AuPd crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two Zr2AuPd ribbons oriented in the (1, 0, 0) direction. Zr is bonded in a linear geometry to one Pd and one Au atom. The Zr–Pd bond length is 2.44 Å. The Zr–Au bond length is 2.77 Å. Pd is bonded in a linear geometry to two equivalent Zr atoms. Au is bonded in a linear geometry to two equivalent Zr atoms.
ZrPdAu2 crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two ZrPdAu2 ribbons oriented in the (1, 0, 0) direction. Zr is bonded in a linear geometry to two equivalent Au atoms. Both Zr–Au bond lengths are 2.58 Å. Pd is bonded in a linear geometry to two equivalent Au atoms. Both Pd–Au bond lengths are 2.59 Å. Au is bonded in a linear geometry to one Zr and one Pd atom.