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DOE OSTI2020

Materials Data on Li2PbAu by Materials Project

Li2AuPb is Zintl Phase-derived structured and crystallizes in the cubic F-43m space group. The structure is three-dimensional. there are two inequivalent Li sites. In the first Li site, Li is bonded to four equivalent Pb atoms to form distorted corner-sharing LiPb4 tetrahedra. All Li–Pb bond lengths are 2.92 Å. In the second Li site, Li is bonded to four equivalent Au atoms to form distorted corner-sharing LiAu4 tetrahedra. All Li–Au bond lengths are 2.92 Å. Au is bonded in a distorted body-centered cubic geometry to four equivalent Li and four equivalent Pb atoms. All Au–Pb bond lengths are 2.92 Å. Pb is bonded in a 8-coordinate geometry to four equivalent Li and four equivalent Au atoms.

36 MATERIALS SCIENCE↗

DOE OSTI2020

Materials Data on LiPbAu2 by Materials Project

LiAu2Pb crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two LiAu2Pb ribbons oriented in the (1, 0, 0) direction. Li is bonded in a linear geometry to two equivalent Au atoms. Both Li–Au bond lengths are 2.52 Å. Au is bonded in a linear geometry to one Li and one Pb atom. The Au–Pb bond length is 2.76 Å. Pb is bonded in a linear geometry to two equivalent Au atoms.

36 MATERIALS SCIENCE↗