Materials Data on Pd(AuF4)2 by Materials Project
Pd(AuF4)2 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. Pd2+ is bonded in an octahedral geometry to six F1- atoms. There are a spread of Pd–F bond distances ranging from 2.17–2.19 Å. Au3+ is bonded in a rectangular see-saw-like geometry to four F1- atoms. There are a spread of Au–F bond distances ranging from 1.95–2.00 Å. There are four inequivalent F1- sites. In the first F1- site, F1- is bonded in a bent 120 degrees geometry to one Pd2+ and one Au3+ atom. In the second F1- site, F1- is bonded in a distorted bent 150 degrees geometry to one Pd2+ and one Au3+ atom. In the third F1- site, F1- is bonded in a bent 120 degrees geometry to one Pd2+ and one Au3+ atom. In the fourth F1- site, F1- is bonded in a single-bond geometry to one Au3+ atom.