Materials Data on AsXe2OF10 by Materials Project
(XeF2)4(AsF6)2O2 crystallizes in the tetragonal I4/mcm space group. The structure is zero-dimensional and consists of four water molecules, four AsF6 clusters, and eight XeF2 clusters. In each AsF6 cluster, As is bonded in an octahedral geometry to six equivalent F atoms. All As–F bond lengths are 1.78 Å. F is bonded in a single-bond geometry to one As atom. In each XeF2 cluster, Xe is bonded in a linear geometry to two equivalent F atoms. Both Xe–F bond lengths are 2.09 Å. F is bonded in a single-bond geometry to one Xe atom.
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