Results for “AsH3C(SF2)3”

Materials Data on AsH3C(SF2)3 by Materials Project

CH3S3AsF6 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six methanetrithiol molecules and six AsF6 clusters. In each AsF6 cluster, As5+ is bonded in an octahedral geometry to six F1- atoms. There is two shorter (1.77 Å) and four longer (1.78 Å) As–F bond length. There are three inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one As5+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one As5+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one As5+ atom.