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Materials Data on As4HN2(ClO3)2 by Materials Project

(N2)2H2(As2O3)4(Cl2)2 crystallizes in the hexagonal P6/mmm space group. The structure is two-dimensional and consists of two hydrochloric acid molecules; one hydrogen molecule; two As2O3 sheets oriented in the (0, 0, 1) direction; and one N2 sheet oriented in the (0, 0, 1) direction. In each As2O3 sheet, As+4.50+ is bonded in a distorted T-shaped geometry to three equivalent O2- atoms. All As–O bond lengths are 1.81 Å. O2- is bonded in a bent 120 degrees geometry to two equivalent As+4.50+ atoms. In the N2 sheet, N+2.50- is bonded in a distorted trigonal planar geometry to three equivalent N+2.50- atoms. All N–N bond lengths are 3.08 Å.

36 MATERIALS SCIENCE↗