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Materials Data on AsF3 by Materials Project

AsF3 crystallizes in the orthorhombic Pna2_1 space group. The structure is zero-dimensional and consists of four trifluoroarsine molecules. As3+ is bonded in a distorted T-shaped geometry to three F1- atoms. There is one shorter (1.77 Å) and two longer (1.78 Å) As–F bond length. There are three inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one As3+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one As3+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one As3+ atom.

36 MATERIALS SCIENCE↗

Materials Data on AsF5 by Materials Project

AsF5 crystallizes in the hexagonal P6_3/mmc space group. The structure is zero-dimensional and consists of two AsF5 clusters. As5+ is bonded in a trigonal bipyramidal geometry to five F1- atoms. There is three shorter (1.72 Å) and two longer (1.75 Å) As–F bond length. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one As5+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one As5+ atom.

36 MATERIALS SCIENCE↗