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An assessment of ocean alkalinity enhancement using aqueous hydroxides: kinetics, efficiency, and precipitation thresholds

Abstract. Ocean alkalinity enhancement (OAE) is a promising approach to marine carbon dioxide removal (mCDR) that leverages the large surface area and carbon storage capacity of the oceans to sequester atmospheric CO2 as dissolved bicarbonate (HCO3-). One OAE method involves the conversion of salt in seawater into aqueous alkalinity (NaOH), which is returned to the ocean. The resulting increase in seawater pH and alkalinity causes a shift in dissolved inorganic carbon (DIC) speciation toward carbonate and a decrease in the surface ocean pCO2. The shift in the pCO2 results in enhanced uptake of atmospheric CO2 by the seawater due to gas exchange. In this study, we systematically test the efficiency of CO2 uptake in seawater treated with NaOH at aquarium (15 L) and tank (6000 L) scales to establish operational boundaries for safety and efficiency in advance of scaling up to field experiments. CO2 equilibration occurred on the order of weeks to months, depending on circulation, air forcing, and air bubbling conditions within the test tanks. An increase of ∼0.7–0.9 mol DIC per mol added alkalinity (in the form of NaOH) was observed through analysis of seawater bottle samples and pH sensor data, consistent with the value expected given the values of the carbonate system equilibrium calculations for the range of salinities and temperatures tested. Mineral precipitation occurred when the bulk seawater pH exceeded 10.0 and Ωaragonite exceeded 30.0. This precipitation was dominated by Mg(OH)2 over hours to 1 d before shifting to CaCO3,aragonite precipitation. These data, combined with models of the dilution and advection of alkaline plumes, will allow the estimation of the amount of carbon dioxide removal expected from OAE pilot studies. Future experiments should better approximate field conditions including sediment interactions, biological activity, ocean circulation, air–sea gas exchange rates, and mixing zone dynamics.

Ringham, Mallory C. (ORCID:0000000348020185)↗

STS-77 Flight Day 5

On this fifth day of the STS-77 mission, the flight crew, Cmdr. John H. Casper, Pilot Curtis L. Brown, Jr., and Mission Specialists Andrew S.W. Thomas, Ph.D., Daniel W. Bursch, Mario Runco, Jr., and Marc Garneau, Ph.D., spend the first half of their workday assisting payload controllers with investigations into materials processing of samples and the growth of crystals. The progress of starfish and mussel development in a spaceborne aquarium in the Spacehab module in the Shuttle's cargo bay is seen. The crew then move off in different directions to support work with many of the experiments that make up the fourth mission of the Spacehab pressurized module. Endeavour is about 64 miles away from the Passive Aerodynamically Stabilized Magnetically Damped Satellite-Satellite Test Unit, or PAMS-STU, which was deployed from a canister in the payload bay on day four. Since mission day five coincided with Memorial Day , the crew started the 'Indy 500' from earth orbit.

Source record↗

Illusory sensations in aircraft flight and weightlessness

Clearly misleading illusions only appear when the vestibular input is of a nonconflicting nature. A number of experiments with blind goldfish were conducted since the vestibular system of the goldfish is homologous in many respects to that of man. Inertial stimuli were given by linear acceleration of the entire aquarium with the fish in it. A high-speed movie camera and three-axis accelerometers were used to record the fish responses. It was found that fish, if subjected to horizontal linear acceleration, behave as if the moving force acting on the otoliths were a gravitational force component and not an inertial reacting force.

Von Baumgarten, R. J.↗