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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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ION Validation of Transformational CO2 Capture Solvent Technology with Revolutionary Stability: “Project Apollo”

This final report presents all the work and tests performed during ION’s carbon dioxide (CO2) capture pilot test campaign at the 0.6 MWe scale in the Pilot Solvent Test Unit (PSTU) at the National Carbon Capture Center (NCCC): “Validation of Transformational CO2 Capture Solvent Technology with Revolutionary Stability,” referred to as the “Apollo” Project (DE-FE0031727).

Meuleman, Erik↗

Demonstration of High-Temperature Calcium-Based Thermochemical Energy Storage System for use with Concentrating Solar Power Facilities

Thermochemical energy storage (TCES) systems offer several advantages over sensible heat storage via molten salts for concentrating solar power (CSP) including: energy density, cost, indefinite storage time, and no risk of freezing. SR’s TCES system utilizes a CaO-based carbonation reaction at high temperature in a fixed bed heat exchanger reactor. The SunShot APOLLO project focuses on the validation of the calcium oxide sorbent for capacity, durability, system economics, and demonstration of the system at a small pilot scale, including system control and operation in simulated on-sun conditions, discharging at 720°C. Under phase I SR completed evaluation of the sorbent loaded in a single-channel heat exchanger reactor. The major accomplishments of phase II are: Design, fabrication and commissioning of a 4 kWhth pilot plant (50x capacity increase from previous bench scale) with a closed-loop CO 2 system, and a commercially relevant heat exchange reactor. The heat exchange reactor has been designed with state-of-the-art modeling tools to ensure 1) sufficient lifetime of the Incoloy body and 2) performance of the packed bed reactor will be adequate to meet the milestones. The rest of the pilot system has been designed with off-the shelf components to maximize reliability and cost effectiveness. The system is highly instrumented and capable of time resolved, independent measurements of the heat and mass balances respectively. Major developments in the technoeconomic analysis (TEA) include 1) reduction of the cost of membrane gas storage for the near-term and future systems and 2) integration with liquid metal receivers and particle receivers for higher decarbonation temperatures and pressures which reduced the cost of gas compression and increased system efficiency. The result are three scenarios with costs bases of 21.9 dollars, 14.3 dollars, and 10.9 dollars/kWh th corresponding to a real LCOE of 59, 57, 56 dollars/MW he , respectively. The basic operations of the energy storage system were demonstrated for carbonation (discharging) and decarbonation (charging) over short time periods. Excellent control of the CO 2 mass balance across the reactor was achieved with mass flow controllers and the basic operation of the level control of the CO 2 gas bladder was achieved. The system was apparently free from leaks and operated continuously for 18 days with no mechanical failures, thus meeting milestone 2.5.5. The major shortcomings of the system had to do with the controls which prevented us from deep cycling and or reaching high cycles. We were unable to decarbonate (charge) the system for more than a few minutes at a time, which was much shorter than the design target of 10 hrs. This issue could not be resolved due to facility availability and contract closure. One major finding is that CaO-based TCES is most cost efficient when charged with HTF (heat transfer fluid) temperatures >850°C to reach the round-trip exergy efficiency and system cost targets which are higher temperatures than those considered for Gen 3 CSP. Many of the balance of plant components do not exist today, however we are encouraged by our findings that in general with more work we are able to reduce the capital cost, for example with the membrane gas storage, which is an innovative component in itself. The CaO-based TCES system has potential to meet the latest SunShot 2030 goals of LCOE at 50 $/MW he with capital costs of <11/kWh th .

14 SOLAR ENERGY↗

Demonstration of High-Temperature Calcium-Based Thermochemical Energy Storage System for use with Concentrating Solar Power Facilities

Thermochemical energy storage (TCES) systems offer several advantages over sensible heat storage via molten salts for concentrating solar power (CSP) including: energy density, cost, indefinite storage time, and no risk of freezing. SR’s TCES system utilizes a CaO-based carbonation reaction at high temperature in a fixed bed heat exchanger reactor. The SunShot APOLLO project focuses on the validation of the calcium oxide sorbent for capacity, durability, system economics, and demonstration of the system at a small pilot scale, including system control and operation in simulated on-sun conditions, discharging at 720°C. Under phase I SR completed evaluation of the sorbent loaded in a single-channel heat exchanger reactor. The major accomplishments of phase II are: Design, fabrication and commissioning of a 4 kWhth pilot plant (50x capacity increase from previous bench scale) with a closed-loop CO 2 system, and a commercially relevant heat exchange reactor. The heat exchange reactor has been designed with state-of-the-art modeling tools to ensure 1) sufficient lifetime of the Incoloy body and 2) performance of the packed bed reactor will be adequate to meet the milestones. The rest of the pilot system has been designed with off-the shelf components to maximize reliability and cost effectiveness. The system is highly instrumented and capable of time resolved, independent measurements of the heat and mass balances respectively. Major developments in the technoeconomic analysis (TEA) include 1) reduction of the cost of membrane gas storage for the near-term and future systems and 2) integration with liquid metal receivers and particle receivers for higher decarbonation temperatures and pressures which reduced the cost of gas compression and increased system efficiency. The result are three scenarios with costs bases of 21.9 dollars, 14.3 dollars, and 10.9 dollars/kWhth corresponding to a real LCOE of 59, 57, 56 dollars/MWhe, respectively. The basic operations of the energy storage system were demonstrated for carbonation (discharging) and decarbonation (charging) over short time periods. Excellent control of the CO 2 mass balance across the reactor was achieved with mass flow controllers and the basic operation of the level control of the CO 2 gas bladder was achieved. The system was apparently free from leaks and operated continuously for 18 days with no mechanical failures, thus meeting milestone 2.5.5. The major shortcomings of the system had to do with the controls which prevented us from deep cycling and or reaching high cycles. We were unable to decarbonate (charge) the system for more than a few minutes at a time, which was much shorter than the design target of 10 hrs. This issue could not be resolved due to facility availability and contract closure. One major finding is that CaO-based TCES is most cost efficient when charged with HTF (heat transfer fluid) temperatures >850°C to reach the round-trip exergy efficiency and system cost targets which are higher temperatures than those considered for Gen 3 CSP. Many of the balance of plant components do not exist today, however we are encouraged by our findings that in general with more work we are able to reduce the capital cost, for example with the membrane gas storage, which is an innovative component in itself. The CaO-based TCES system has potential to meet the latest SunShot 2030 goals of LCOE at 50 dollars/MWhe with capital costs of <11/kWhth.

14 SOLAR ENERGY↗

Apollo

Apollo’s project goal will be a system to aid workers at nuclear/industrial facilities by adding an intuitive tool to easily and accurately track and identify changes in a wide variety of workflow situations.

Lancaster, GregoryD.↗

Sodium Ion Expansion Power Block for Distributed CSP

The Sodium Ion Expansion Power Block for Distributed CSP was a three-plus-one-year effort under the Concentrating Solar Power: Advanced Projects Offering Low LCOE Opportunities (CSP: APOLLO) funding program within the U.S. Department of Energy Solar Energy Technologies Office. The primary objective of this project is to develop a dual-stage modular sodium thermal electrochemical converter (Na-TEC) heat engine power block, which can be potentially integrated with either a small-scale dish solar or large-scale heliostats and parabolic trough CSP. Na-TEC is a heat engine that generates electricity through the isothermal expansion of sodium ions. The Na-TEC is a closed system that can theoretically achieve conversion efficiencies above 45% when operating between thermal reservoirs at 1150 K and 550 K. However, thermal designs have confined previous single-stage devices to thermal efficiencies below 20%. To mitigate some of these limitations, we consider dividing the isothermal expansion into two stages; one at the evaporator temperature (1150 K) and another at an intermediate temperature (650 K –1050 K). This dual-stage Na-TEC takes advantage of regeneration and reheating, and could be amenable to better thermal management. In light of this, we first designed and developed a thermo-electrochemical model, and thermodynamically demonstrated how the dual-stage device can improve the efficiency by up to 8% points over the best performing single-stage device. We also established an application regime map for the single- and dual-stage Na-TEC in terms of the power density and the total thermal parasitic loss. Moreover, a thermal design of an axisymmetric dual-stage Na-TEC is developed to guide the scale-up and fabrication of sub-components of prototype module. A reduced-order finite-element model is used in conjunction with a Na-TEC thermodynamic model that was developed to determine the total parasitic heat loss of this dual-stage design. A number of simplifications are applied in the reduced-order model to decrease the computational time while maintaining acceptable accuracy. According to this analysis, a maximum efficiency of 29% and a maximum power output of 125 W can be achieved. Ultimately, we were able to demonstrate thermal efficiency improvements of the Na-TEC heat engine from 19% up to 40.3%, in a dual-stage (non-optimized) prototype module that we designed, fabricated, and tested with high temperature stage at 923 K. Furthermore, a cost-performance analysis for this improved dual-stage design was carried out for distributed-CSP systems. A high-level techno-economic analysis (TEA) explores four scenarios where a Na-TEC is used as the heat engine for a distributed-CSP system. Overnight capital cost and levelized cost of electricity (LCOE) are estimated for a system lifetime of 30 years, revealing that overnight capital costs in a range from $3.57 to $17.71 per We are feasible, which equate to LCOEs from 6.9 to 17.2 cents/kWh e -1 . This analysis makes a significant contribution by concurrently quantifying the efficiency and unit costs for a range of multistage configurations, and demonstrating that a Na-TEC may be a promising alternative to Stirling engines for distributed-CSP systems at residential scale of 1–5 kW e .

14 SOLAR ENERGY↗

Project Earthrise: Proceedings of the Ninth Annual Conference of in VIVO Planetary Health

The “Earthrise” photograph, taken on the 1968 Apollo 8 mission, became one of the most significant images of the 20th Century. It triggered a profound shift in environmental awareness and the potential for human unity—inspiring the first Earth Day in 1970. Taking inspiration from these events 50 years later, we initiated Project Earthrise at our 2020 annual conference of inVIVO Planetary Health. This builds on the emergent concept of planetary health, which provides a shared narrative to integrate rich and diverse approaches from all aspects of society towards shared solutions to global challenges. The acute catastrophe of the COVID-19 pandemic has drawn greater attention to many other interconnected global health, environmental, social, spiritual, and economic problems that have been underappreciated or neglected for decades. This is accelerating opportunities for greater collaborative action, as many groups now focus on the necessity of a “Great Transition”. While ambitious integrative efforts have never been more important, it is imperative to apply these with mutualistic value systems as a compass, as we seek to make wiser choices. Project Earthrise is our contribution to this important process. This underscores the imperative for creative ecological solutions to challenges in all systems, on all scales with advancing global urbanization in the digital age—for personal, environmental, economic and societal health alike. At the same time, our agenda seeks to equally consider our social and spiritual ecology as it does natural ecology. Revisiting the inspiration of “Earthrise”, we welcome diverse perspectives from across all dimensions of the arts and the sciences, to explore novel solutions and new normative values. Building on academic rigor, we seek to place greater value on imagination, kindness and mutualism as we address our greatest challenges, for the health of people, places and planet.

interdependence↗

Longitudinal Solid P Longitudinal Solid Polarized Target for CL get for CLAS12 and Study of Spin AS12 and Study of Spin Structure of Nucleons

A suite of experiments measuring target-spin observables in electron-nucleon scattering (dubbed Run Group C) was conducted at Jefferson Lab's Hall B in Newport News, VA with a new polarized nuclear target known as 'APOLLO' (Ammonia POLarized LOngitudinally). This innovative target is engineered to seamlessly integrate with the advanced 12GeV CEBAF (Continuous Electron Beam Accelerator Facility) accelerator and the Hall B CLAS12 (12 GeV CEBAF Large Acceptance Spectrometer) detector array. The 'APOLLO' target harnesses the power of Dynamic Nuclear Polarization (DNP) to achieve longitudinal polarization of solid ammonia, thereby creating a net polarization in both protons (NH3) and deuterons (ND3). These samples are subjected to a 5 Tesla magnetic field produced by the CLAS12 spectrometer central solenoid, cooled to 1 K using helium evaporation, and subsequently exposed to microwave radiation at a frequency of 140 GHz. This project was made possible through a collaborative partnership between the Jefferson Lab Target Group, Old Dominion University, University of Virginia, Christopher Newport University, and the CLAS Collaboration. Integrating the APOLLO target into CLAS12 presented unique challenges because of its specific spatial and dimensional constraints. This dissertation will highlight the innovative solutions developed to address these challenges, including the creation of a new target material transport system, the incorporation of superconducting magnetic correction coils, and the development of a customized Nuclear Magnetic Resonance (NMR) system. In addition to a detailed description of the development and operation of APOLLO, and an overview of RGC, this document also describes the global data fitting of proton asymmetries in the Deep Inelastic scattering (DIS) and the Resonance regions, and it offers insights into the comprehensive analysis of target polarization data.

Pandey, Pushpa↗

Development of 800°C Integrated Flow Channel Ceramic Receiver

The project’s objective was to develop an affordable, efficient power tower receiver for future concentrated solar power plants consistent with the SunShot APOLLO goal of 6¢/kWhe for the levelized cost of electricity (LCOE). A conceptual design was generated with the goal of meeting the SunShot objectives for the receiver for performance (≥720°C fluid outlet and ≥90% thermal efficiency), cost (≤$150/kWt), and lifetime (10,000 cycles). The higher temperature design leveraged the development of a new solar absorber coating capable of operating at 800°C with greater capability than state-of-the-art Pyromark paint. An industrial process was developed to manufacture the coating on a large scale (hundreds of gallons) and apply the coating using industrial spray equipment as currently used on our commercial receivers.

14 SOLAR ENERGY↗

Argonne Leadership Computing Facility 2024 Operational Assessment Report

This Operational Assessment Report describes how the Argonne Leadership Computing Facility (ALCF) met or exceeded every goal set by DOE for the calendar year (CY) 2024. In CY 2024, the ALCF operated Polaris, an AMD and NVIDIA-based Hewlett Packard Enterprise (HPE) Apollo 6500 Gen10+ system that provides a powerful platform for breakthrough science and prepares applications and workloads for Aurora, Argonne National Laboratory’s Intel-HPE exascale computer. Since going into production in August 2022, Polaris has supported research teams from the DOE Exascale Computing Project (ECP), which concluded in 2024, and from ALCF’s Aurora Early Science Program (ESP). Polaris delivered a total of 2555.7K node-hours to 17 Innovative and Novel Computational Impact on Theory and Experiment (INCITE) 2024 projects and 601.6K node-hours to ASCR Leadership Computing Challenge (ALCC) projects (12 of which were awarded during the 2023–2024 ALCC year and 11 of which were awarded during the 2024–2025 ALCC year), as well as providing substantial time for Director’s Discretionary (DD) projects (966.2K node-hours). As Table ES.1 shows, Polaris performed exceptionally well in terms of overall availability (97.7 percent), scheduled availability (99.6 percent), and utilization (94.7 percent; Table 2.1). In CY 2024, ALCF supported more than 2,000 users. As of March 18, 2025, ALCF’s users have published 254 papers in peer-reviewed journals and technical proceedings.

97 MATHEMATICS AND COMPUTING↗

High-temperature seals for supercritical carbon-dioxide (sCO 2 ) turbines (Final Report)

This is the final report for project DE-FE0031924 titled “High-temperature seals for supercritical carbon-dioxide (sCO 2 ) turbines.” The report provides a summary of the entire project efforts from October 2020 through December 2024 including the high-temperature commercial dry gas seal (DGS) tests and thermal modeling of Task 2, as well as the high-temperature, large-diameter seal design and high-temperature tests of large-diameter seals in Task 3. A key outcome of Task 2 was the testing completion of specially instrumented commercial DGS in the GE-SwRI Apollo sCO 2 compressor (27,000 rpm). Test data from the DGS showed elevated temperatures upwards of 350 o F, which are close to the higher operating temperature limit of the DGS. The temperature measurements provide insight into the expected thermal loads on DGS operating in high-speed sCO 2 compressor and provided test data for validation of an in-house thermal model of the compressor/seal. Under Task 2.0, this report also presents the development of a steady-state conjugate heat-transfer model of the DGS operating in the sCO 2 compressor – a first of its kind model for modeling heat transfer of sCO 2 in an actual operating compressor. The findings of the thermal model show a reasonable match between temperature predictions of the model and the measured temperature data, also pointing out the validity of the approach and assumptions made in modeling the flows, heat transfer coefficients and windage modeling in the rig. Under Task 3.0, this report presents the preliminary design of a large-diameter hybrid face seal (14 inch and 26-inch diameter) for field testing in a land-based GE turbine. The preliminary seal design effort presented in this report under project DE-FE0031924 builds on the development and successful laboratory testing for such large diameter hybrid face seal under the prior DE-FE0024007 project. Key aspects of seal fluid analyses with CFD, mechanical design considerations and assembly considerations in a land-based turbine are presented. Finally, under Task 3.0, this report also presents the continued high-temperature testing of the 14-inch diameter hybrid face seal developed previously under the DE-FE0024007 program. Specifically, test data demonstrating successful non-contact seal operation and seal effective leakage of 0.001-inch with seal inlet temperatures above 700 o F are presented in this report. Successful hybrid seal operation in a laboratory environment for a large diameter (14-inch) seal at temperatures above 700 o F is a major technological milestone for this technology.

01 COAL, LIGNITE, AND PEAT↗

Proliferation of Interstellar Plutonium into the Solar System

The astrophysical site of production of actinides in the galaxy has long been debated. Recently, neutron star mergers have been shown to produce actinides, though their contribution to the total amount is unknown. A second site, Type II supernovae, likely also contributes. The relative frequencies and production totals of these two sources lead to two very different and distinguishable predictions for the contemporary concentration of actinides in the local interstellar medium. This project was aimed at measuring live cosmological 244 Pu in lunar soil in order to infer the current interstellar concentration of Pu for comparison with the concentration inferred in the early solar system 4.5 billion years ago. This requires detecting Pu in lunar soil at a concentration of 10 4 – 10 5 atoms/g. We developed Pu separation and detection methodologies that exceed the current state of the art by ~100× and are now capable of making this extremely challenging measurement in principle. Based on that success we obtained a sample of lunar soil from the Apollo 17 mission. We have not yet analyzed it owing to difficulties in quantitatively and reproducibly transferring such minute quantities of Pu from the separation step to the analysis step. Once this technical issue is resolved we will be able to analyze the lunar soil.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

2020 Virtual Theoretical Division Lightning Talk Series

All members of the Theoretical Division Community, students, staff members, group leaders, division management and other interested individuals are invited to come and support the various Lightning Talk presentations.

36 MATERIALS SCIENCE↗

The OSIRIS-REx Sample Return Capsule re-entry: A coordinated seismo-acoustic observational campaign for the study of meteor phenomena

Objects entering Earth’s atmosphere at hypersonic velocities may generate powerful acoustic waves. Depending on atmospheric conditions and acoustic propagation paths, they may be captured using ground or balloon-borne microbarometers and microphones. Impacts into the Earth’s atmosphere by asteroids in a meter-size range are sporadic and unannounced, and thus, well-documented scientific observations of asteroids are rare and generally happen by chance. Arriving from interplanetary space at hypervelocity, spacecraft are considered analogues for low velocity meteoroids and asteroids impacting the Earth’s atmosphere, and as such provide unprecedented and unique opportunity to carry out planned observational campaigns and perform detailed studies of meteor phenomena. However, since the end of the Apollo era, only four instances of a hypersonic re-entry of an artificial body from interplanetary space with an incident speed of 11-12 km/s have been observed and studied. These were the Sample Return Capsules (SRCs) that brought physical samples of extraterrestrial material back to Earth (Genesis, Stardust, Hayabusa 1, Hayabusa 2). These re-entries were also detected by infrasound and/or seismic sensors. The next opportunity to observe an artificial meteor will be on 24 September 2023 with the re-entry of NASA’s OSIRIS-REx SRC that will bring samples of the carbonaceous near-Earth asteroid Bennu. The re-entry consists of several flight phases, including hypersonic and supersonic, providing a unique opportunity to observe these by infrasound and seismic sensors. We will discuss observational campaign efforts aimed to capture geophysical signals generated by the OSIRIS-REx SRC re-entry. This campaign utilizes an unparalleled number of instruments, both ground and airborne, strategically positioned in the immediate and extended region around the projected re-entry trajectory to maximize the scientific output.

47 - OTHER INSTRUMENTATION↗

Radioisotope Power Systems: Considerations for use of Dynamic versus Static Conversion Technologies for NASA Missions

For more than five decades, Radioisotope Power Systems (RPS) have played a critical role in the exploration of space, enabling missions of scientific discovery to destinations across the solar system by providing electrical power to explore remote, challenging and extreme environments. In particular, RPS enable deep space missions where increased heliocentric distances reduce the ability of solar power to adequately meet spacecraft and instruments power requirements. Some previous notable missions that were enabled by RPS include Nimbus III, the Apollo Sur-face Experiments, the Pioneers 10 and 11, the Viking Mars Landers, Galileo, Ulysses, Cassini, New Horizons and Curiosity. The current operating set of missions that are enabled by RPS are Voyagers 1 and 2, Cassini, New Hori-zons, and Curiosity. The Multi-Mission Radioisotope Thermal Generator (MMRTG) is the current RPS used for mis-sions. An enhanced version of this generator outfitted with higher efficiency thermoelectrics is under development for potential use in the future. There are also current development efforts underway by NASA to explore dynamic power conversion systems such as Brayton and Stirling. This paper will compare and contrast the pros and cons of a generalized dynamic system with the current state-of-the-art thermoelectric static conversion system. The reason for this paper is to calmly analyze the pros and cons so that all the pertinent factors are placed under the same examination light with equal brightness. As with any purchase made the “newness” of certain items sometimes overrides a needed desire to fully vet all characteristics of the merchandise so that the best choice is made. The following areas will be specifically examined and discussed as they may impact the choice of radioisotope power system for a specific mission: • Projected power output to weight ratio (We/kg) • Amount of Pu-238 required per a fixed power output • Excess heat available to be rejected or used • Fueling operations during assembly by the Department of Energy (DOE) • Planetary protection protocol during fueling and testing of RPS • Transportation operations from DOE assembly site to Kennedy Space Center (KSC) • Remote operations at KSC prior to launch during Assembly Test and Launch Operations (ATLO) phase o Timing of the placement of the RPS onto spacecraft/rover o Off-normal operations at KSC

99 GENERAL AND MISCELLANEOUS↗