Materials Data on Al9Rh2 by Materials Project
Al9Rh2 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. Rh is bonded in a 9-coordinate geometry to nine Al atoms. There are a spread of Rh–Al bond distances ranging from 2.46–2.61 Å. There are five inequivalent Al sites. In the first Al site, Al is bonded in a linear geometry to two equivalent Rh atoms. In the second Al site, Al is bonded in a 2-coordinate geometry to two equivalent Rh atoms. In the third Al site, Al is bonded in a 2-coordinate geometry to two equivalent Rh atoms. In the fourth Al site, Al is bonded in a distorted bent 120 degrees geometry to two equivalent Rh atoms. In the fifth Al site, Al is bonded in a distorted bent 150 degrees geometry to two equivalent Rh atoms.
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