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Materials Data on TmAlGa by Materials Project

TmGaAl crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. Tm is bonded in a 10-coordinate geometry to six equivalent Ga and six equivalent Al atoms. There are a spread of Tm–Ga bond distances ranging from 3.07–3.45 Å. There are a spread of Tm–Al bond distances ranging from 3.11–3.37 Å. Ga is bonded in a 10-coordinate geometry to six equivalent Tm, one Ga, and three equivalent Al atoms. The Ga–Ga bond length is 2.73 Å. There are two shorter (2.58 Å) and one longer (2.81 Å) Ga–Al bond lengths. Al is bonded in a 10-coordinate geometry to six equivalent Tm, three equivalent Ga, and one Al atom. The Al–Al bond length is 2.71 Å.

36 MATERIALS SCIENCE↗

Materials Data on TmAlGa by Materials Project

TmGaAl is hexagonal omega structure-derived structured and crystallizes in the hexagonal P-6m2 space group. The structure is three-dimensional. Tm is bonded to six equivalent Ga and six equivalent Al atoms to form a mixture of edge and face-sharing TmAl6Ga6 cuboctahedra. All Tm–Ga bond lengths are 3.10 Å. All Tm–Al bond lengths are 3.10 Å. Ga is bonded in a 9-coordinate geometry to six equivalent Tm and three equivalent Al atoms. All Ga–Al bond lengths are 2.58 Å. Al is bonded in a 3-coordinate geometry to six equivalent Tm and three equivalent Ga atoms.

36 MATERIALS SCIENCE↗