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Mineralogy and petrography of HAL, an isotopically-unusual Allende inclusion

Results of a detailed mineralogical and textural study of the HAL (Hibonite ALlende) inclusion of the Allende meteorite, which has been found to exhibit no Mg-26 excesses despite very high Al-27/Mg-24 ratios and large fractionation effects with small nuclear effects in its Ca, are reported. The inclusion is found to consist of three up to 1-mm diameter hibonite crystals partially surrounded by a black rim resembling a devitrified glass and containing an anisotropic Al-Fe oxide, which is in turn surrounded by a 2-mm thick friable rim sequence consisting of five layers distinguishable by mineral composition. From the available evidence, it is concluded that each of the layers of the friable rim formed by the accretion of an assemblage of condensate grains rather than by the complete reaction of a HAL precursor with a nebular gas, thus explaining its unusual isotopic characteristics and supporting the conclusion that the solar nebular contained isotopically-distinct reservoirs.

Allen, J. M.↗

Solubility of hydrogen in metals and its effect of pore-formation and embrittlement

The effect of alloying elements on hydrogen solubility were determined by evaluating solubility equations and interaction coefficients. The solubility of dry hydrogen at one atmosphere was investigated in liquid aluminum, Al-Ti, Al-Si, Al-Fe, liquid gold, Au-Cu, and Au-Pd. The design of rapid heating and high pressure casting furnaces used in meta foam experiments is discussed as well as the mechanism of precipitation of pores in melts, and the effect of hydrogen on the shrinkage porosity of Al-Cu and Al-Si alloys. Hydrogen embrittlement in iron base alloys is also examined.

Shahani, H. R.↗

Edge-restraint deformation processing of aluminides and other powders

The novel, 'edge-restraint rolling' method has been developed in order to facilitate the thickness reduction of brittle, high strength alloys to the degree of thin plates or sheets, by first hot-compacting the prealloyed powders into billets and conducting the thickness reduction in a series of reheats and roll passes. Attention is presently given to the cases of equiatomic aluminide FeAl, (Ni,Fe)3Al, and an Al-Fe alloy. The flat-rolled products thus obtained may lead to the development of components not otherwise formable for powerplant and other aerospace applications.

Bhattacharyya, S.↗

Rapid solidification of highly undercooled liquids

Melt undercooling is considered as a fundamental processing parameter for powders and for melt-spun and surface-melted samples. With reference to experimental results for Mn, Al, Al-Be, Al-Fe, and InSb-Sb powders, it is shown that the undercooling behavior in droplets is influenced by powder size, coating, melt superheat, and cooling rate. Droplet sample microstructures can be compared directly with those of rapidly quenched powders to establish the application of laboratory-scale studies to large-scale processing.

Perepezko, J. H.↗

Twin Knudsen Cell Configuration for Activity Measurements by Mass Spectrometry

A twin Knudsen cell apparatus for alloy activity measurements by mass spectrometry is described. Two Knudsen cells - one containing an alloy and one containing a pure component - are mounted on a single flange and translated into the sampling region via a motorized x-y table. Mixing of the molecular beams from the cells is minimized by a novel system of shutters. Activity measurements were taken on two well-characterized alloys to verify the operation of the system. Silver activity measurements are reported for Ag-Cu alloys and aluminum activity measurements are reported for Fe-Al alloys. The temperature dependence of activity for a 0.474 mol fraction Al-Fe alloy gives a partial molar heat of aluminum. Measurements taken with the twin cell show good agreement with literature values for these alloys.

Jacobson, N. S.↗