Materials Data on AgSbO12 by Materials Project
AgSbO12 crystallizes in the tetragonal P4_2/n space group. The structure is two-dimensional and consists of two AgSbO12 sheets oriented in the (0, 0, 1) direction. Ag is bonded in a square co-planar geometry to four equivalent O atoms. All Ag–O bond lengths are 2.21 Å. Sb is bonded in a tetrahedral geometry to four equivalent O atoms. All Sb–O bond lengths are 1.92 Å. There are three inequivalent O sites. In the first O site, O is bonded in a distorted bent 120 degrees geometry to two O atoms. There is one shorter (1.25 Å) and one longer (1.89 Å) O–O bond length. In the second O site, O is bonded in a bent 120 degrees geometry to one Ag and one O atom. In the third O site, O is bonded in a distorted single-bond geometry to one Sb and one O atom.