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All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Materials Data on AgN3 by Materials Project

AgN3 crystallizes in the orthorhombic Ibam space group. The structure is two-dimensional and consists of two AgN3 sheets oriented in the (0, 0, 1) direction. Ag1+ is bonded in a distorted square co-planar geometry to four equivalent N+0.33- atoms. All Ag–N bond lengths are 2.40 Å. There are two inequivalent N+0.33- sites. In the first N+0.33- site, N+0.33- is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ag1+ and one N+0.33- atom. The N–N bond length is 1.19 Å. In the second N+0.33- site, N+0.33- is bonded in a linear geometry to two equivalent N+0.33- atoms.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on AgN3 by Materials Project

AgN3 crystallizes in the orthorhombic Ibam space group. The structure is three-dimensional. Ag1+ is bonded in a 8-coordinate geometry to eight equivalent N+0.33- atoms. There are four shorter (2.66 Å) and four longer (2.74 Å) Ag–N bond lengths. There are two inequivalent N+0.33- sites. In the first N+0.33- site, N+0.33- is bonded in a 1-coordinate geometry to four equivalent Ag1+ and one N+0.33- atom. The N–N bond length is 1.19 Å. In the second N+0.33- site, N+0.33- is bonded in a linear geometry to two equivalent N+0.33- atoms.

36 MATERIALS SCIENCE↗