Materials Data on AgIO2 by Materials Project
AgO2I crystallizes in the tetragonal I4_1/a space group. The structure is three-dimensional. Ag is bonded to six equivalent O atoms to form edge-sharing AgO6 octahedra. There are a spread of Ag–O bond distances ranging from 2.38–2.60 Å. O is bonded to three equivalent Ag and two equivalent I atoms to form a mixture of distorted edge and corner-sharing OAg3I2 trigonal bipyramids. There are one shorter (2.24 Å) and one longer (2.25 Å) O–I bond lengths. I is bonded in a distorted square co-planar geometry to four equivalent O atoms.
36 MATERIALS SCIENCE↗