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AgHg crystallizes in the cubic P2_13 space group. The structure is three-dimensional. Ag is bonded in a 7-coordinate geometry to seven equivalent Hg atoms. There are a spread of Ag–Hg bond distances ranging from 2.91–3.00 Å. Hg is bonded in a 7-coordinate geometry to seven equivalent Ag atoms.
AgHg is Tetraauricupride structured and crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. Ag is bonded in a body-centered cubic geometry to eight equivalent Hg atoms. All Ag–Hg bond lengths are 2.99 Å. Hg is bonded in a body-centered cubic geometry to eight equivalent Ag atoms.