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AgClO2 crystallizes in the triclinic P1 space group. The structure is two-dimensional and consists of one hydrogen peroxide molecule and one AgCl sheet oriented in the (0, 0, 1) direction. In the AgCl sheet, Ag is bonded in a trigonal planar geometry to three equivalent Cl atoms. There are one shorter (2.50 Å) and two longer (2.53 Å) Ag–Cl bond lengths. Cl is bonded in a trigonal planar geometry to three equivalent Ag atoms.
AgClO2 crystallizes in the monoclinic C2/c space group. The structure is one-dimensional and consists of four hydrogen peroxide molecules and two AgCl ribbons oriented in the (-1, 0, 1) direction. In each AgCl ribbon, Ag is bonded in a linear geometry to two equivalent Cl atoms. Both Ag–Cl bond lengths are 2.40 Å. Cl is bonded in an L-shaped geometry to two equivalent Ag atoms.
AgO2Cl crystallizes in the orthorhombic Pcca space group. The structure is two-dimensional and consists of one AgO2Cl sheet oriented in the (0, 0, 1) direction. Ag is bonded to six equivalent O atoms to form a mixture of distorted edge and corner-sharing AgO6 pentagonal pyramids. There are a spread of Ag–O bond distances ranging from 2.45–2.66 Å. O is bonded to three equivalent Ag and one Cl atom to form a mixture of edge and corner-sharing OAg3Cl trigonal pyramids. The O–Cl bond length is 1.60 Å. Cl is bonded in a water-like geometry to two equivalent O atoms.
AgO2Cl crystallizes in the orthorhombic Cmme space group. The structure is one-dimensional and consists of two AgO2Cl ribbons oriented in the (0, 1, 0) direction. Ag is bonded in a 4-coordinate geometry to four equivalent O atoms. There are two shorter (2.27 Å) and two longer (2.46 Å) Ag–O bond lengths. O is bonded in a distorted T-shaped geometry to two equivalent Ag and one Cl atom. The O–Cl bond length is 1.60 Å. Cl is bonded in a water-like geometry to two equivalent O atoms.
AgO2Cl crystallizes in the triclinic P1 space group. The structure is two-dimensional and consists of one AgO2Cl sheet oriented in the (-1, 1, 0) direction. there are two inequivalent Ag sites. In the first Ag site, Ag is bonded in a linear geometry to two O atoms. There are one shorter (2.11 Å) and one longer (2.12 Å) Ag–O bond lengths. In the second Ag site, Ag is bonded in a square co-planar geometry to four O atoms. There are a spread of Ag–O bond distances ranging from 2.10–2.18 Å. There are four inequivalent O sites. In the first O site, O is bonded in a distorted trigonal planar geometry to two Ag and one Cl atom. The O–Cl bond length is 1.90 Å. In the second O site, O is bonded in a bent 120 degrees geometry to one Ag and one Cl atom. The O–Cl bond length is 1.57 Å. In the third O site, O is bonded in a bent 120 degrees geometry to one Ag and one Cl atom. The O–Cl bond length is 1.57 Å. In the fourth O site, O is bonded in a distorted trigonal planar geometry to two Ag and one Cl atom. The O–Cl bond length is 1.91 Å. There are two inequivalent Cl sites. In the first Cl site, Cl is bonded in a distorted bent 120 degrees geometry to two O atoms. In the second Cl site, Cl is bonded in a linear geometry to two O atoms.
AgO2Cl crystallizes in the monoclinic P2_1/m space group. The structure is two-dimensional and consists of one AgO2Cl sheet oriented in the (0, 0, 1) direction. Ag is bonded to one O and five equivalent Cl atoms to form a mixture of edge and corner-sharing AgCl5O octahedra. The corner-sharing octahedral tilt angles are 3°. The Ag–O bond length is 2.75 Å. There are four shorter (2.71 Å) and one longer (2.87 Å) Ag–Cl bond lengths. There are two inequivalent O sites. In the first O site, O is bonded in a bent 120 degrees geometry to one Ag and one O atom. The O–O bond length is 1.24 Å. In the second O site, O is bonded in a single-bond geometry to one O atom. Cl is bonded to five equivalent Ag atoms to form a mixture of edge and corner-sharing ClAg5 square pyramids.
AgO2Cl crystallizes in the monoclinic C2/m space group. The structure is two-dimensional and consists of two AgO2Cl sheets oriented in the (1, 0, 0) direction. Ag is bonded to two equivalent O and four equivalent Cl atoms to form a mixture of edge and corner-sharing AgCl4O2 octahedra. The corner-sharing octahedra tilt angles range from 5–68°. Both Ag–O bond lengths are 2.74 Å. There are two shorter (2.64 Å) and two longer (2.71 Å) Ag–Cl bond lengths. O is bonded in a bent 120 degrees geometry to one Ag and one O atom. The O–O bond length is 1.24 Å. Cl is bonded in a see-saw-like geometry to four equivalent Ag atoms.