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DOE OSTI2020

Materials Data on AgBrO2 by Materials Project

AgBrO2 crystallizes in the monoclinic P2_1/m space group. The structure is two-dimensional and consists of two hydrogen peroxide molecules and one AgBr sheet oriented in the (0, 0, 1) direction. In the AgBr sheet, Ag is bonded in a 5-coordinate geometry to five equivalent Br atoms. There are a spread of Ag–Br bond distances ranging from 2.85–2.88 Å. Br is bonded to five equivalent Ag atoms to form a mixture of distorted corner and edge-sharing BrAg5 square pyramids.

36 MATERIALS SCIENCE↗

DOE OSTI2020

Materials Data on AgBrO2 by Materials Project

AgBrO2 crystallizes in the monoclinic C2/c space group. The structure is one-dimensional and consists of four hydrogen peroxide molecules and two AgBr ribbons oriented in the (-1, 0, 1) direction. In each AgBr ribbon, Ag is bonded in a linear geometry to two equivalent Br atoms. Both Ag–Br bond lengths are 2.53 Å. Br is bonded in a distorted L-shaped geometry to two equivalent Ag atoms.

36 MATERIALS SCIENCE↗