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Materials Data on AgBF4 by Materials Project

AgBF4 crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Ag1+ is bonded in a 10-coordinate geometry to ten F1- atoms. There are a spread of Ag–F bond distances ranging from 2.59–3.05 Å. B3+ is bonded in a tetrahedral geometry to four F1- atoms. There are a spread of B–F bond distances ranging from 1.40–1.43 Å. There are three inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Ag1+ and one B3+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to three equivalent Ag1+ and one B3+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to three equivalent Ag1+ and one B3+ atom.

36 MATERIALS SCIENCE↗