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Materials Data on AgAuS2 by Materials Project

AuAgS2 crystallizes in the orthorhombic Pccm space group. The structure is three-dimensional. Au3+ is bonded in a linear geometry to two equivalent S2- atoms. Both Au–S bond lengths are 2.31 Å. Ag1+ is bonded in a 4-coordinate geometry to four equivalent S2- atoms. All Ag–S bond lengths are 2.62 Å. S2- is bonded to one Au3+, two equivalent Ag1+, and one S2- atom to form a mixture of edge and corner-sharing SAg2AuS tetrahedra. The S–S bond length is 2.13 Å.

36 MATERIALS SCIENCE↗