Materials Data on AgAsF6 by Materials Project
AgAsF6 crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Ag1+ is bonded to six equivalent F1- atoms to form AgF6 octahedra that share corners with six equivalent AsF6 octahedra. The corner-sharing octahedral tilt angles are 0°. All Ag–F bond lengths are 2.45 Å. As5+ is bonded to six equivalent F1- atoms to form AsF6 octahedra that share corners with six equivalent AgF6 octahedra. The corner-sharing octahedral tilt angles are 0°. All As–F bond lengths are 1.78 Å. F1- is bonded in a distorted linear geometry to one Ag1+ and one As5+ atom.