Materials Data on Ag5CF4 by Materials Project
Ag5CF4 crystallizes in the tetragonal P-4 space group. The structure is three-dimensional. there are six inequivalent Ag+1.20+ sites. In the first Ag+1.20+ site, Ag+1.20+ is bonded in a 5-coordinate geometry to one C2- and four F1- atoms. The Ag–C bond length is 2.15 Å. There are a spread of Ag–F bond distances ranging from 2.33–2.69 Å. In the second Ag+1.20+ site, Ag+1.20+ is bonded in a 4-coordinate geometry to four F1- atoms. There are a spread of Ag–F bond distances ranging from 2.38–2.68 Å. In the third Ag+1.20+ site, Ag+1.20+ is bonded in a 6-coordinate geometry to one C2- and five F1- atoms. The Ag–C bond length is 2.17 Å. There are a spread of Ag–F bond distances ranging from 2.24–2.92 Å. In the fourth Ag+1.20+ site, Ag+1.20+ is bonded in a 6-coordinate geometry to one C2- and five F1- atoms. The Ag–C bond length is 2.16 Å. There are a spread of Ag–F bond distances ranging from 2.21–2.95 Å. In the fifth Ag+1.20+ site, Ag+1.20+ is bonded in a 4-coordinate geometry to four F1- atoms. There are two shorter (2.38 Å) and two longer (2.52 Å) Ag–F bond lengths. In the sixth Ag+1.20+ site, Ag+1.20+ is bonded in a 4-coordinate geometry to six F1- atoms. There are a spread of Ag–F bond distances ranging from 2.46–2.96 Å. C2- is bonded in a 4-coordinate geometry to three Ag+1.20+ and one C2- atom. The C–C bond length is 1.32 Å. There are four inequivalent F1- sites. In the first F1- site, F1- is bonded in a 6-coordinate geometry to six Ag+1.20+ atoms. In the second F1- site, F1- is bonded in a 6-coordinate geometry to six Ag+1.20+ atoms. In the third F1- site, F1- is bonded in a 6-coordinate geometry to six Ag+1.20+ atoms. In the fourth F1- site, F1- is bonded in a 5-coordinate geometry to five Ag+1.20+ atoms.