Materials Data on Ag3F8 by Materials Project
Ag(AgF4)2 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. there are two inequivalent Ag+2.67+ sites. In the first Ag+2.67+ site, Ag+2.67+ is bonded in a rectangular see-saw-like geometry to four F1- atoms. There is two shorter (1.96 Å) and two longer (2.00 Å) Ag–F bond length. In the second Ag+2.67+ site, Ag+2.67+ is bonded in a distorted octahedral geometry to six F1- atoms. There are a spread of Ag–F bond distances ranging from 2.12–2.58 Å. There are four inequivalent F1- sites. In the first F1- site, F1- is bonded in a distorted bent 120 degrees geometry to two Ag+2.67+ atoms. In the second F1- site, F1- is bonded in a single-bond geometry to one Ag+2.67+ atom. In the third F1- site, F1- is bonded in a bent 120 degrees geometry to two Ag+2.67+ atoms. In the fourth F1- site, F1- is bonded in a distorted single-bond geometry to two Ag+2.67+ atoms.