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Materials Data on Ag2MoO4 by Materials Project

Ag2MoO4 is Spinel structured and crystallizes in the cubic Fd-3m space group. The structure is three-dimensional. Mo6+ is bonded to four equivalent O2- atoms to form MoO4 tetrahedra that share corners with twelve equivalent AgO6 octahedra. The corner-sharing octahedral tilt angles are 50°. All Mo–O bond lengths are 1.81 Å. Ag1+ is bonded to six equivalent O2- atoms to form AgO6 octahedra that share corners with six equivalent MoO4 tetrahedra and edges with six equivalent AgO6 octahedra. All Ag–O bond lengths are 2.51 Å. O2- is bonded in a 4-coordinate geometry to one Mo6+ and three equivalent Ag1+ atoms.

36 MATERIALS SCIENCE↗