Materials Data on Ag2IO6 by Materials Project
Ag2O6I crystallizes in the trigonal R-3 space group. The structure is two-dimensional and consists of three Ag2O6I sheets oriented in the (0, 0, 1) direction. Ag is bonded in a distorted trigonal planar geometry to three equivalent O atoms. All Ag–O bond lengths are 2.18 Å. O is bonded in a bent 120 degrees geometry to one Ag and one I atom. The O–I bond length is 1.89 Å. I is bonded in an octahedral geometry to six equivalent O atoms.
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