Materials Data on Ag2H12S(NO)4 by Materials Project
(Ag(NH3)2)2SO4 crystallizes in the tetragonal P-42_1c space group. The structure is zero-dimensional and consists of two sulfuric acid molecules and four Ag(NH3)2 clusters. In each Ag(NH3)2 cluster, Ag1+ is bonded in a linear geometry to two equivalent N1- atoms. Both Ag–N bond lengths are 2.14 Å. N1- is bonded in a distorted trigonal non-coplanar geometry to one Ag1+ and three H1+ atoms. All N–H bond lengths are 1.03 Å. There are three inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one N1- atom. In the second H1+ site, H1+ is bonded in a single-bond geometry to one N1- atom. In the third H1+ site, H1+ is bonded in a single-bond geometry to one N1- atom.
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