Materials Data on Ag13OsO6 by Materials Project
Ag13OsO6 crystallizes in the cubic Fm-3c space group. The structure is three-dimensional. Os1- is bonded in an octahedral geometry to six equivalent O2- atoms. All Os–O bond lengths are 1.92 Å. There are two inequivalent Ag1+ sites. In the first Ag1+ site, Ag1+ is bonded in a cuboctahedral geometry to twelve equivalent Ag1+ atoms. All Ag–Ag bond lengths are 2.84 Å. In the second Ag1+ site, Ag1+ is bonded in a 2-coordinate geometry to one Ag1+ and two equivalent O2- atoms. Both Ag–O bond lengths are 2.51 Å. O2- is bonded in a 1-coordinate geometry to one Os1- and four equivalent Ag1+ atoms.
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