Materials Data on Si(AgP)2 by Materials Project
Si(AgP)2 crystallizes in the tetragonal I-42d space group. The structure is three-dimensional. Ag1+ is bonded in a distorted trigonal planar geometry to three equivalent P1+ atoms. There are one shorter (2.53 Å) and two longer (2.56 Å) Ag–P bond lengths. Si4- is bonded to four equivalent P1+ atoms to form corner-sharing SiP4 tetrahedra. All Si–P bond lengths are 2.26 Å. P1+ is bonded in a 2-coordinate geometry to three equivalent Ag1+ and two equivalent Si4- atoms.