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NaPd2Ag crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two NaPd2Ag ribbons oriented in the (1, 0, 0) direction. Na is bonded in a linear geometry to two equivalent Pd atoms. Both Na–Pd bond lengths are 2.74 Å. Pd is bonded in a linear geometry to one Na and one Ag atom. The Pd–Ag bond length is 2.63 Å. Ag is bonded in a linear geometry to two equivalent Pd atoms.
NaPdAg2 crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two NaPdAg2 ribbons oriented in the (1, 0, 0) direction. Na is bonded in a linear geometry to two equivalent Ag atoms. Both Na–Ag bond lengths are 2.85 Å. Pd is bonded in a linear geometry to two equivalent Ag atoms. Both Pd–Ag bond lengths are 2.63 Å. Ag is bonded in a linear geometry to one Na and one Pd atom.