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NaAg2 is Cubic Laves structured and crystallizes in the cubic Fd-3m space group. The structure is three-dimensional. Na is bonded in a 12-coordinate geometry to twelve equivalent Ag atoms. All Na–Ag bond lengths are 3.34 Å. Ag is bonded to six equivalent Na and six equivalent Ag atoms to form a mixture of edge, face, and corner-sharing AgNa6Ag6 cuboctahedra. All Ag–Ag bond lengths are 2.85 Å.
NaAg3 is Uranium Silicide-like structured and crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Na is bonded to twelve Ag atoms to form a mixture of corner, edge, and face-sharing NaAg12 cuboctahedra. There are four shorter (3.00 Å) and eight longer (3.02 Å) Na–Ag bond lengths. There are two inequivalent Ag sites. In the first Ag site, Ag is bonded to four equivalent Na atoms to form a mixture of distorted corner and edge-sharing AgNa4 cuboctahedra. In the second Ag site, Ag is bonded in a distorted square co-planar geometry to four equivalent Na atoms.
Na3Ag is alpha bismuth trifluoride structured and crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. there are two inequivalent Na sites. In the first Na site, Na is bonded in a 4-coordinate geometry to four equivalent Na and four equivalent Ag atoms. All Na–Na bond lengths are 3.31 Å. All Na–Ag bond lengths are 3.31 Å. In the second Na site, Na is bonded to eight equivalent Na and four equivalent Ag atoms to form NaNa8Ag4 cuboctahedra that share corners with four equivalent NaNa8Ag4 cuboctahedra, corners with eight equivalent AgNa12 cuboctahedra, edges with eight equivalent NaNa8Ag4 cuboctahedra, faces with four equivalent NaNa8Ag4 cuboctahedra, and faces with six equivalent AgNa12 cuboctahedra. All Na–Ag bond lengths are 3.53 Å. Ag is bonded to twelve Na atoms to form AgNa12 cuboctahedra that share corners with four equivalent AgNa12 cuboctahedra, corners with eight equivalent NaNa8Ag4 cuboctahedra, edges with eight equivalent AgNa12 cuboctahedra, faces with four equivalent AgNa12 cuboctahedra, and faces with six equivalent NaNa8Ag4 cuboctahedra.
Na3Ag is Uranium Silicide-like structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. Na is bonded in a distorted see-saw-like geometry to four equivalent Ag atoms. There are two shorter (3.32 Å) and two longer (3.43 Å) Na–Ag bond lengths. Ag is bonded to twelve equivalent Na atoms to form a mixture of corner and face-sharing AgNa12 cuboctahedra.
Na3Ag is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. there are two inequivalent Na sites. In the first Na site, Na is bonded to four equivalent Na and four equivalent Ag atoms to form a mixture of distorted face, edge, and corner-sharing NaNa4Ag4 tetrahedra. All Na–Na bond lengths are 3.29 Å. All Na–Ag bond lengths are 3.29 Å. In the second Na site, Na is bonded in a 8-coordinate geometry to eight equivalent Na and six equivalent Ag atoms. All Na–Ag bond lengths are 3.80 Å. Ag is bonded in a body-centered cubic geometry to fourteen Na atoms.
NaAg3 is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Na is bonded to twelve equivalent Ag atoms to form a mixture of face and corner-sharing NaAg12 cuboctahedra. All Na–Ag bond lengths are 3.00 Å. Ag is bonded in a distorted square co-planar geometry to four equivalent Na atoms.