Materials Data on AgTeNO5 by Materials Project
AgNTeO5 crystallizes in the orthorhombic Pbcn space group. The structure is three-dimensional. Ag1+ is bonded in a 2-coordinate geometry to six O2- atoms. There are a spread of Ag–O bond distances ranging from 2.36–2.75 Å. N5+ is bonded in a trigonal planar geometry to three O2- atoms. There is two shorter (1.26 Å) and one longer (1.29 Å) N–O bond length. Te4+ is bonded in a 4-coordinate geometry to four equivalent O2- atoms. There are two shorter (1.96 Å) and two longer (2.12 Å) Te–O bond lengths. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted trigonal planar geometry to one Ag1+ and two equivalent Te4+ atoms. In the second O2- site, O2- is bonded in a distorted single-bond geometry to one Ag1+ and one N5+ atom. In the third O2- site, O2- is bonded in a single-bond geometry to two equivalent Ag1+ and one N5+ atom.