Materials Data on AgRuF7 by Materials Project
RuAgF7 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. Ru6+ is bonded in an octahedral geometry to six F1- atoms. There are a spread of Ru–F bond distances ranging from 1.86–1.96 Å. Ag1+ is bonded in a 6-coordinate geometry to six F1- atoms. There are a spread of Ag–F bond distances ranging from 2.06–2.88 Å. There are seven inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Ru6+ atom. In the second F1- site, F1- is bonded in a bent 150 degrees geometry to two equivalent Ag1+ atoms. In the third F1- site, F1- is bonded in a single-bond geometry to one Ru6+ atom. In the fourth F1- site, F1- is bonded in a distorted bent 150 degrees geometry to one Ru6+ and one Ag1+ atom. In the fifth F1- site, F1- is bonded in a distorted bent 150 degrees geometry to one Ru6+ and one Ag1+ atom. In the sixth F1- site, F1- is bonded in a 2-coordinate geometry to one Ru6+ and one Ag1+ atom. In the seventh F1- site, F1- is bonded in a single-bond geometry to one Ru6+ and one Ag1+ atom.