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Ag2F is trigonal omega structured and crystallizes in the trigonal P-3m1 space group. The structure is two-dimensional and consists of one Ag2F sheet oriented in the (0, 0, 1) direction. Ag is bonded in a 3-coordinate geometry to three equivalent F atoms. All Ag–F bond lengths are 2.51 Å. F is bonded to six equivalent Ag atoms to form distorted edge-sharing FAg6 octahedra.
AgF2 crystallizes in the orthorhombic Pbca space group. The structure is three-dimensional. Ag2+ is bonded to six equivalent F1- atoms to form distorted corner-sharing AgF6 octahedra. The corner-sharing octahedra tilt angles range from 45–70°. There are four shorter (2.12 Å) and two longer (2.75 Å) Ag–F bond lengths. F1- is bonded in a 3-coordinate geometry to three equivalent Ag2+ atoms.
Ag2F5 crystallizes in the triclinic P-1 space group. The structure is three-dimensional. there are six inequivalent Ag+2.50+ sites. In the first Ag+2.50+ site, Ag+2.50+ is bonded in a distorted square co-planar geometry to four F1- atoms. There are two shorter (2.05 Å) and two longer (2.13 Å) Ag–F bond lengths. In the second Ag+2.50+ site, Ag+2.50+ is bonded to six F1- atoms to form distorted corner-sharing AgF6 octahedra. The corner-sharing octahedra tilt angles range from 31–49°. There are a spread of Ag–F bond distances ranging from 2.04–2.62 Å. In the third Ag+2.50+ site, Ag+2.50+ is bonded to six F1- atoms to form corner-sharing AgF6 octahedra. The corner-sharing octahedra tilt angles range from 26–64°. There are a spread of Ag–F bond distances ranging from 2.08–2.37 Å. In the fourth Ag+2.50+ site, Ag+2.50+ is bonded in a square co-planar geometry to four F1- atoms. There is two shorter (1.96 Å) and two longer (2.00 Å) Ag–F bond length. In the fifth Ag+2.50+ site, Ag+2.50+ is bonded to six F1- atoms to form distorted corner-sharing AgF6 octahedra. The corner-sharing octahedra tilt angles range from 26–64°. There are a spread of Ag–F bond distances ranging from 2.00–2.73 Å. In the sixth Ag+2.50+ site, Ag+2.50+ is bonded in a square co-planar geometry to four F1- atoms. There are a spread of Ag–F bond distances ranging from 1.95–2.00 Å. There are ten inequivalent F1- sites. In the first F1- site, F1- is bonded in a bent 120 degrees geometry to two Ag+2.50+ atoms. In the second F1- site, F1- is bonded in a 2-coordinate geometry to two Ag+2.50+ atoms. In the third F1- site, F1- is bonded in a single-bond geometry to one Ag+2.50+ atom. In the fourth F1- site, F1- is bonded in a distorted bent 120 degrees geometry to two Ag+2.50+ atoms. In the fifth F1- site, F1- is bonded in a bent 150 degrees geometry to two Ag+2.50+ atoms. In the sixth F1- site, F1- is bonded in a bent 150 degrees geometry to two Ag+2.50+ atoms. In the seventh F1- site, F1- is bonded in a distorted bent 120 degrees geometry to two Ag+2.50+ atoms. In the eighth F1- site, F1- is bonded in a bent 150 degrees geometry to two Ag+2.50+ atoms. In the ninth F1- site, F1- is bonded in a distorted trigonal planar geometry to three Ag+2.50+ atoms. In the tenth F1- site, F1- is bonded in a distorted single-bond geometry to two Ag+2.50+ atoms.
Ag(AgF4)2 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. there are two inequivalent Ag+2.67+ sites. In the first Ag+2.67+ site, Ag+2.67+ is bonded in a rectangular see-saw-like geometry to four F1- atoms. There is two shorter (1.96 Å) and two longer (2.00 Å) Ag–F bond length. In the second Ag+2.67+ site, Ag+2.67+ is bonded in a distorted octahedral geometry to six F1- atoms. There are a spread of Ag–F bond distances ranging from 2.12–2.58 Å. There are four inequivalent F1- sites. In the first F1- site, F1- is bonded in a distorted bent 120 degrees geometry to two Ag+2.67+ atoms. In the second F1- site, F1- is bonded in a single-bond geometry to one Ag+2.67+ atom. In the third F1- site, F1- is bonded in a bent 120 degrees geometry to two Ag+2.67+ atoms. In the fourth F1- site, F1- is bonded in a distorted single-bond geometry to two Ag+2.67+ atoms.
AgF is Halite, Rock Salt structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Ag1+ is bonded to six equivalent F1- atoms to form a mixture of edge and corner-sharing AgF6 octahedra. The corner-sharing octahedral tilt angles are 0°. All Ag–F bond lengths are 2.51 Å. F1- is bonded to six equivalent Ag1+ atoms to form a mixture of edge and corner-sharing FAg6 octahedra. The corner-sharing octahedral tilt angles are 0°.
AgF2 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. Ag2+ is bonded to six equivalent F1- atoms to form a mixture of corner and edge-sharing AgF6 octahedra. The corner-sharing octahedra tilt angles range from 44–58°. There are a spread of Ag–F bond distances ranging from 2.12–2.62 Å. F1- is bonded in a 3-coordinate geometry to three equivalent Ag2+ atoms.
Ag2F3 is Corundum structured and crystallizes in the trigonal R-3c space group. The structure is three-dimensional. Ag+1.50+ is bonded to six equivalent F1- atoms to form a mixture of edge, face, and corner-sharing AgF6 octahedra. The corner-sharing octahedra tilt angles range from 47–58°. There are three shorter (2.32 Å) and three longer (2.41 Å) Ag–F bond lengths. F1- is bonded to four equivalent Ag+1.50+ atoms to form a mixture of distorted edge and corner-sharing FAg4 trigonal pyramids.