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Li2AgCu crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two Li2AgCu ribbons oriented in the (1, 0, 0) direction. Li is bonded in a linear geometry to one Ag and one Cu atom. The Li–Ag bond length is 2.56 Å. The Li–Cu bond length is 2.43 Å. Ag is bonded in a linear geometry to two equivalent Li atoms. Cu is bonded in a linear geometry to two equivalent Li atoms.
LiAg2Cu crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two LiAg2Cu ribbons oriented in the (1, 0, 0) direction. Li is bonded in a linear geometry to two equivalent Ag atoms. Both Li–Ag bond lengths are 2.54 Å. Ag is bonded in a linear geometry to one Li and one Cu atom. The Ag–Cu bond length is 2.46 Å. Cu is bonded in a linear geometry to two equivalent Ag atoms.