Materials Data on Ag4Te(ClO3)2 by Materials Project
(Ag2O3Cl)2Te crystallizes in the cubic P2_13 space group. The structure is three-dimensional and consists of four tellurium molecules and one Ag2O3Cl framework. In the Ag2O3Cl framework, there are two inequivalent Ag2+ sites. In the first Ag2+ site, Ag2+ is bonded in a 4-coordinate geometry to three equivalent O2- and one Cl1- atom. All Ag–O bond lengths are 2.73 Å. The Ag–Cl bond length is 2.83 Å. In the second Ag2+ site, Ag2+ is bonded in a water-like geometry to two O2- atoms. There are one shorter (2.38 Å) and one longer (2.55 Å) Ag–O bond lengths. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a 3-coordinate geometry to two Ag2+ and one Cl1- atom. The O–Cl bond length is 1.52 Å. In the second O2- site, O2- is bonded in a bent 120 degrees geometry to one Ag2+ and one Cl1- atom. The O–Cl bond length is 1.50 Å. There are two inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a distorted trigonal non-coplanar geometry to one Ag2+ and three equivalent O2- atoms. In the second Cl1- site, Cl1- is bonded in a trigonal non-coplanar geometry to three equivalent O2- atoms.