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Materials Data on ZnCdAg2 by Materials Project

Ag2CdZn crystallizes in the orthorhombic Cmm2 space group. The structure is three-dimensional. there are two inequivalent Ag sites. In the first Ag site, Ag is bonded in a 8-coordinate geometry to two equivalent Ag and two equivalent Zn atoms. Both Ag–Ag bond lengths are 2.85 Å. Both Ag–Zn bond lengths are 2.68 Å. In the second Ag site, Ag is bonded in a 10-coordinate geometry to eight Ag and two equivalent Cd atoms. There are four shorter (2.96 Å) and two longer (3.07 Å) Ag–Ag bond lengths. Both Ag–Cd bond lengths are 2.97 Å. Cd is bonded in a 10-coordinate geometry to two equivalent Ag, six equivalent Cd, and two equivalent Zn atoms. There are four shorter (2.96 Å) and two longer (3.07 Å) Cd–Cd bond lengths. Both Cd–Zn bond lengths are 2.87 Å. Zn is bonded in a 8-coordinate geometry to two equivalent Ag and two equivalent Cd atoms.

36 MATERIALS SCIENCE↗

Materials Data on ZnCdAg2 by Materials Project

Ag2CdZn crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two Ag2CdZn ribbons oriented in the (1, 0, 0) direction. Ag is bonded in a linear geometry to one Cd and one Zn atom. The Ag–Cd bond length is 2.79 Å. The Ag–Zn bond length is 2.53 Å. Cd is bonded in a linear geometry to two equivalent Ag atoms. Zn is bonded in a linear geometry to two equivalent Ag atoms.

36 MATERIALS SCIENCE↗

Materials Data on ZnCdAg2 by Materials Project

Ag2CdZn crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. Ag is bonded in a distorted body-centered cubic geometry to four equivalent Cd and four equivalent Zn atoms. All Ag–Cd bond lengths are 2.97 Å. All Ag–Zn bond lengths are 2.75 Å. Cd is bonded in a distorted body-centered cubic geometry to eight equivalent Ag atoms. Zn is bonded in a body-centered cubic geometry to eight equivalent Ag atoms.

36 MATERIALS SCIENCE↗