Materials Data on AgCSN by Materials Project
AgSCN crystallizes in the orthorhombic Pnnm space group. The structure is three-dimensional. Ag1+ is bonded in a 4-coordinate geometry to one N3- and three equivalent S2- atoms. The Ag–N bond length is 2.20 Å. There are two shorter (2.60 Å) and one longer (2.80 Å) Ag–S bond lengths. C4+ is bonded in a distorted linear geometry to one N3- and one S2- atom. The C–N bond length is 1.18 Å. The C–S bond length is 1.66 Å. N3- is bonded in a distorted bent 150 degrees geometry to one Ag1+ and one C4+ atom. S2- is bonded to three equivalent Ag1+ and one C4+ atom to form distorted corner-sharing SAg3C trigonal pyramids.