Materials Data on RbCdAg3(CN)6 by Materials Project
RbAg3Cd(CN)6 crystallizes in the trigonal P312 space group. The structure is three-dimensional. Rb1+ is bonded to six equivalent N3- atoms to form distorted RbN6 octahedra that share edges with three equivalent CdN6 octahedra. All Rb–N bond lengths are 3.10 Å. Ag1+ is bonded in a linear geometry to two equivalent C2+ atoms. Both Ag–C bond lengths are 2.05 Å. Cd2+ is bonded to six equivalent N3- atoms to form CdN6 octahedra that share edges with three equivalent RbN6 octahedra. All Cd–N bond lengths are 2.37 Å. C2+ is bonded in a linear geometry to one Ag1+ and one N3- atom. The C–N bond length is 1.17 Å. N3- is bonded in a 3-coordinate geometry to one Rb1+, one Cd2+, and one C2+ atom.
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