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At least 19 records

An x ray scatter approach for non-destructive chemical analysis of low atomic numbered elements

A non-destructive x-ray scatter (XRS) approach has been developed, along with a rapid atomic scatter algorithm for the detection and analysis of low atomic-numbered elements in solids, powders, and liquids. The present method of energy dispersive x-ray fluorescence spectroscopy (EDXRF) makes the analysis of light elements (i.e., less than sodium; less than 11) extremely difficult. Detection and measurement become progressively worse as atomic numbers become smaller, due to a competing process called 'Auger Emission', which reduces fluorescent intensity, coupled with the high mass absorption coefficients exhibited by low energy x-rays, the detection and determination of low atomic-numbered elements by x-ray spectrometry is limited. However, an indirect approach based on the intensity ratio of Compton and Rayleigh scattered has been used to define light element components in alloys, plastics and other materials. This XRS technique provides qualitative and quantitative information about the overall constituents of a variety of samples.

Ross, H. Richard↗

Diamond like carbon coatings: Categorization by atomic number density

Dense diamond-like hydrocarbon films grown at the NASA Lewis Research Center by radio frequency self bias discharge and by direct ion beam deposition were studied. A new method for categorizing hydrocarbons based on their atomic number density and elemental composition was developed and applied to the diamond-like hydrocarbon films. It was shown that the diamond-like hydrocarbon films are an entirely new class of hydrocarbons with atomic number densities lying between those of single crystal diamond and adamantanes. In addition, a major review article on these new materials was completed in cooperation with NASA Lewis Research Center personnel.

Angus, John C.↗

Solar cell radiation response near the interface of different atomic number materials

The response of cobalt 60 irradiated N/P silicon solar cells was measured as a function of the atomic number of the medium adjacent to the cell and the direction of the gamma ray beam. The interpositioning of various thicknesses of aluminum between the adjacent material and the cell had the effect of moving the cell to various locations in an approximate monatomic numbered medium. Using this technique the solar cell response was determined at various distances from the interface for gold and beryllium. The results were compared with predictions based upon ionization chamber measurements of dose perturbations in aluminum and found to agree within five percent. Ionization chamber data was then used to estimate the influence of various base contact materials.

Burke, E. A.↗

Cosmic-ray abundances of elements with atomic number 26 less than or equal to 40 measured on HEAO 3

Individual elements in the cosmic radiation of even atomic number (Z) in the interval 26-40 have been resolved and their relative abundances measured. The results are inconsistent with a cosmic-ray source whose composition in this charge interval is dominated by r-process nucleosynthesis. The ratios of cosmic-ray source abundances to solar system abundances in this interval follow the same general correlation with first ionization potential as for the lighter elements, although there are deviations in detail.

Binns, W. R.↗

K-LL Auger transition probabilities for elements with low and intermediate atomic numbers

Radiationless K-LL transition probabilities have been calculated nonrelativistically in j-j coupling and in intermediate coupling, without and with configuration interaction, for elements with atomic numbers from 13 to 47. The system is treated as a coupled two-hole configuration. The single-particle radial wave functions required in the calculation of radial matrix elements, and in the calculation of mixing coefficients in the intermediate-coupling scheme, were obtained from Green's atomic independent-particle model. Comparison with previous theoretical work and with experimental data is made. The effects of intermediate coupling, configuration interaction, and relativity are noted.

Chen, M. H.↗

Element Abundances in the Galactic Cosmic Rays with Atomic Number (Z) in the Interval 30 is less than or equal to Z is less than or equal to 40

We present new results on the elemental abundances of galactic cosmic rays with atomic number, Z, greater than 30, and comparison of these observations with abundances expected from galactic propagation of various suggested models of the cosmic-ray source. We combine preliminary results from the 2003-04 flight of the Trans-Iron Galactic Element Recorder (TIGER) cosmic-ray detector with previously reported results from the 2001-02 flight. This instrument flew over Antarctica for nearly 32 days at a mean atmospheric depth of 5.2 mb in December 2001 - January 2002. At the time of submission of this abstract, January 8, 2004, TIGER was again in the air over Antarctica having completed 22 days of an expected 30day flight at a mean atmospheric depth of about 4 nb, Data from the first flight demonstrated excellent resolution of individual elements, and we expect similar resolution from the second flight.

Barbier, Louis↗

Effects of Ion Atomic Number on Single-Event Gate Rupture (SEGR) Susceptibility of Power MOSFETs

The relative importance of heavy-ion interaction with the oxide, charge ionized in the epilayer, and charge ionized in the drain substrate, on the bias for SEGR failure in vertical power MOSFETs is experimentally investigated. The results indicate that both the charge ionized in the epilayer and the ion atomic number are important parameters of SEGR failure. Implications on SEGR hardness assurance are discussed.

Lauenstein, Jean-Marie↗

Photoelectrochemical cells including chalcogenophosphate photoelectrodes

Photoelectrochemical cells employing chalcogenophosphate (MPX3) photoelectrodes are described where M is selected from the group of transition metal series of elements beginning with scandium (atomic number 21) through germanium (atomic number 32) yttrium (atomic number 39) through antimony (atomic number 51) and lanthanum (atomic number 57) through polonium (atomic number 84); P is phosphorus; and X is selected from the chalogenide series consisting of sulfur, selenium, and tellurium. These compounds have bandgaps in the desirable range from 2.0 eV to 2.2 eV for the photoelectrolysis of water and are stable when used as photoelectrodes for the same.

Reichman, B.↗