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At least 19 records

Integration of Experimental Hydroprocessing and FCC Data with Process (Aspen Plus) and Refinery Optimization (Aspen PIMS) Models

NREL's Economic, Sustainability, and Market Analysis (ESMA) team develops process models in Aspen Plus to support techno-economic analysis (TEA) and life-cycle assessment (LCA) of conversion pathways from renewable and circular resources to fuels and chemicals. These tools are being applied to assess probable operational constraints or bottlenecks associated with refinery co-processing and repurposing opportunities. The team also utilizes optimizable refinery models to quantify opportunities for biofuel and bioproduct pathways through integration with existing refining infrastructure. The goals of analysis are to model the transition of refineries to renewable and circular feedstocks and quantify the costs production and CO2 abatement through utilization of existing refineries. At the core of the ESMA team's work is the process data derived from conversion experiments on hydroprocessing and fluid catalytic cracking performed at NREL. The objective of this presentation is to highlight new analysis approaches and capabilities in pathway analysis and refinery optimization modeling with specific emphasis on integration of experimental data.

BIOMASS FUELS,ENERGY PLANNING, POLICY, AND ECONOMY↗

Host tree species mediate corticolous lichen responses to elevated CO 2 and O 3 after 10 years exposure in the Aspen-FACE system

Lichens contribute significantly to the biodiversity and functioning of many ecosystems. Although lichens are useful air pollution bioindicators and may respond in significant ways to global change, they are studied infrequently under field conditions in chamberless exposure systems. We surveyed corticolous lichens on paper birch ( Betula papyrifera ) and trembling aspen ( Populus tremuloides ) after 10 years exposure (1998–2007) to elevated CO 2 (eCO 2 ) and O 3 (eO 3 ) in the Aspen-FACE experiment in Rhinelander, WI, USA. This experiment utilized chamberless exposure rings, 30 m in diameter, with both host trees planted together in one quadrant. Four treatments were allocated among 12 rings: ambient, eCO 2 , eO 3 , and the combination of eCO 2 + eO 3 , each replicated once in each of three blocks. Over the course of the experiment, ambient CO 2 increased from 343 to 386 ppm while eCO 2 averaged ~530 ppm CO 2 . Ambient ozone concentrations averaged ~37 ppb and ~49 ppb for eO 3 although exposures decreased with time. Tree growth and leaf area index were negatively affected by eO 3 and stimulated by eCO 2 , resulting in higher photosynthetically active radiation (PAR) in eO 3 and lower in eCO 2 . We assessed lichen richness and cover on five host trees per ring on the north-facing side of the trunks, which were higher on birch than on aspen. Additionally, neither of the lichen measures on birch responded to the exposure treatments, while on aspen lichen cover was highest in eO 3 and lowest in eCO 2 . On aspen, lichen cover was positively related to PAR and dominated by Caloplaca . No relationship was found for birch, although Lecanora exhibited a negative relationship with PAR. These lichens were insensitive to direct effects of eCO 2 and eO 3 at the levels applied. Instead, they responded to indirect effects, such as host tree species, and changes in understory PAR, resulting from direct effects of eO 3 and eCO 2 on the host trees.

54 ENVIRONMENTAL SCIENCES↗

AmeriFlux FLUXNET-1F US-PFc NW2 Aspen-1 CHEESEHEAD 2019

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-PFc NW2 Aspen-1 CHEESEHEAD 2019. This is the FLUXNET version of the carbon flux data for the site US-PFc NW2 Aspen-1 CHEESEHEAD 2019 produced by applying the standard ONEFlux (1F) software. Site Description - This tower (12m Rohn) is located in the northwestern quadrant of the 10 x 10km study domain. It is located in a forest of short aspen (3m tall). Several older aspen and conifers are interspersed within the regrowing aspen forest (15-20m tall).

Desai, Ankur↗

Haplotype‐resolved genome assembly of Populus tremula × P. alba reveals aspen‐specific megabase satellite DNA

SUMMARY Populus species play a foundational role in diverse ecosystems and are important renewable feedstocks for bioenergy and bioproducts. Hybrid aspen Populus tremula × P. alba INRA 717‐1B4 is a widely used transformation model in tree functional genomics and biotechnology research. As an outcrossing interspecific hybrid, its genome is riddled with sequence polymorphisms which present a challenge for sequence‐sensitive analyses. Here we report a telomere‐to‐telomere genome for this hybrid aspen with two chromosome‐scale, haplotype‐resolved assemblies. We performed a comprehensive analysis of the repetitive landscape and identified both tandem repeat array‐based and array‐less centromeres. Unexpectedly, the most abundant satellite repeats in both haplotypes lie outside of the centromeres, consist of a 147 bp monomer PtaM147, frequently span >1 megabases, and form heterochromatic knobs. PtaM147 repeats are detected exclusively in aspens (section Populus ) but PtaM147‐like sequences occur in LTR‐retrotransposons of closely related species, suggesting their origin from the retrotransposons. The genomic resource generated for this transformation model genotype has greatly improved the design and analysis of genome editing experiments that are highly sensitive to sequence polymorphisms. The work should motivate future hypothesis‐driven research to probe into the function of the abundant and aspen‐specific PtaM147 satellite DNA.

Zhou, Ran↗

Aspen ploidy level and cover maps from NEON Airborne Observation Platform, 2018, Crested Butte, Colorado

Maps of aspen ploidy (diploid or triploid) developed using National Ecological Observatory Network (NEON) Airborne Observation Platform visible to shortwave infrared imaging spectroscopy data that were acquired over the Upper East River, Colorado in 2018. Maps of aspen distribution, as well as other land cover types that were used to screen for aspen dominated pixels are also provided. Each image file is provided as a GeoTiff with internal tiling and LZW compression. For use of ploidy maps, it is necessary to mask out non-aspen and shaded pixels. Shaded pixels are provided in an associated data package. For full details, please see associated publication and methods description. This dataset is associated with the publication in Ecological Applications.

54 ENVIRONMENTAL SCIENCES↗

AmeriFlux US-PFc NW2 Aspen-1 CHEESEHEAD 2019

This is the AmeriFlux version of the carbon flux data for the site US-PFc NW2 Aspen-1 CHEESEHEAD 2019. Site Description - This tower (12m Rohn) is located in the northwestern quadrant of the 10 x 10km study domain. It is located in a forest of short aspen (3m tall). Several older aspen and conifers are interspersed within the regrowing aspen forest (15-20m tall).

Desai, Ankur↗

Use of Renewable Alcohols in Autocatalytic Production of Aspen Organosolv Lignins

This study aimed to investigate the intrinsic efficiency of renewable alcohols, applied under autocatalytic conditions, for removing lignin from aspen and hot-water-extracted aspen while substantially preserving the lignin structure so as to facilitate various valorization strategies. Ethylene glycol (EG), propylene glycol (PG), 1,4-butanediol (BDO), ethanol (EtOH), and tetrahydrofurfuryl alcohol (THFA) were evaluated based on their lignin solubilization ability, expressed as the relative energy difference (RED) following the principles of the Hansen solubility theory. The findings indicate that alcohols with a higher lignin solubilization potential lead to increased delignification, almost 90%, and produce a lignin with a higher content of β-O-4 bonds, up to 68% of those found in aspen milled wood lignin, thereby indicating their potential for valorization through depolymerization. However, these alcohols also produce lignin with a higher content of β-β and β-5 bonds, resulting in a higher molecular weight and polydispersity, due to readily occurring homolytic reactions. Hot-water extraction (HWE) conducted prior to alcohol treatment reduced the delignification efficiency and resulted in a lignin with a lower β-O-4 bond content. The lignins produced in these experiments exhibited a superior UV-A absorption capacity compared with synthetic benzophenone, as well as a greater radical quenching ability than synthetic butylated hydroxytoluene, indicating their potential for use in the protection of polymers against degradation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

AmeriFlux FLUXNET-1F US-PFk SW1 Aspen-2 CHEESEHEAD 2019

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-PFk SW1 Aspen-2 CHEESEHEAD 2019. This is the FLUXNET version of the carbon flux data for the site US-PFk SW1 Aspen-2 CHEESEHEAD 2019 produced by applying the standard ONEFlux (1F) software. Site Description - This tower (32m, trailer-based, telescoping) is located in the southwestern quadrant of the 10 x 10km study domain. It is located in an aspen forest (canopy height: immediate vicinity - 10m; greater area - 24.4 m).

Desai, Ankur↗

AmeriFlux FLUXNET-1F US-PFL SW2 Aspen-3 CHEESEHEAD 2019

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-PFL SW2 Aspen-3 CHEESEHEAD 2019. This is the FLUXNET version of the carbon flux data for the site US-PFL SW2 Aspen-3 CHEESEHEAD 2019 produced by applying the standard ONEFlux (1F) software. Site Description - This tower (25m Rohn) is located in the southwestern quadrant of the 10 x 10km study domain. It is located in an aspen forest (canopy height: 15 - 19.2 m).

Desai, Ankur↗

AmeriFlux FLUXNET-1F US-PFq SE3 Aspen-4 CHEESEHEAD 2019

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-PFq SE3 Aspen-4 CHEESEHEAD 2019. This is the FLUXNET version of the carbon flux data for the site US-PFq SE3 Aspen-4 CHEESEHEAD 2019 produced by applying the standard ONEFlux (1F) software. Site Description - This tower (32m, trailer-based, telescoping) is located in the southeastern quadrant of the 10 x 10km study domain. It is located in an aspen forest (canopy height: 10 - 14.3 m).

Desai, Ankur↗

Calculating the Effects of Solids Input and Removal as a Temperature Control in the Advanced Scale Up Reactor Experiment (ASURE) Facility at NETL Using Aspen

The Advanced Scale Up Reactor Experiment (ASURE) facility at NETL is being designed to be a fuel-flexible multi-purpose reactor that can be used for pyrolysis/gasification or evaluation of other high pressure “circulating fluidized bed” (CFB) chemical processes. The initial system design calculations for pyrolysis/gasification are presented in this work showing the expected performance of the ASURE facility when used as a biomass conversion reactor. Several other areas of application include gasification of any carbonaceous fuel including biomass, coal, plastics, and other waste materials. The reactor can therefore be used to produce SYNGAS of various compositions and hydrogen as well as other high value chemicals resulting from a typical tuned gasification process. This paper discusses an ASPEN model of the facility, focusing on the riser of the CFB reactor and the solids recirculation loop. The ASPEN model divides the riser into two sections. A bottom section which receives ash, char and sand which have been recirculated from a return loop. In this section an inert fluidization gas, (N2 or CO2), is introduced which acts as the primary mover of the solids through the system. The bottom section is equipped with a restricted air feed so that the recirculated char can be partially oxidized. This oxidation process along with the inventory of recirculating sand are used to effectively control the temperature in the following two chemical conversion sections of the reactor which are the pyrolysis zone followed by a tar cracking zone. Fresh fuel is added to the pyrolysis zone and undergoes drying and devolatilization. The products ash, char, volatile matter, and water vapor exit the pyrolysis zone and enter the reaction block for tar cracking. Steam and CO2 gasification reactions will be incorporated into the tar cracking zone, however at the design operating temperature, conversion from these reactions is expected to be essentially zero. The unit when completed in 2026 will test mixtures of biomass, plastics, and waste coal. This presentation discusses the basic ASPEN engineering design model for this project and provides preliminary sensitivity studies to determine how the various parts of the reactor will perform.

ASSURE↗

Remote Sensing Detection of Growing Season Freeze-Induced Defoliation of Montane Quaking Aspen (Populus tremuloides) in Southern Utah, USA

Growing season freeze events pose a threat to quaking aspen (Populus tremuloides Michx.), leading to canopy defoliation, reduced vigor, and increased mortality, especially for declining montane populations western North America. Detecting the spatial distribution and progression of this damage is challenging due to limited in situ observations in this region. This study represents the first attempt to comprehensively resolve the spatial extent of freeze-induced aspen canopy damage in southern Utah using multispectral remote sensing data. We developed an approach to detect the spatial and temporal dynamics of freeze-damaged aspen stands, focusing on a freeze event from 8–9 June 2020 in southern Utah. By integrating medium- (~250 to 500 m) and high-resolution (~10 m) satellite data, we employed the Normalized Difference Vegetation Index (NDVI) to compare post-freeze conditions with historical norms and pre-freeze conditions. Our analysis revealed NDVI reductions of 0.10 to 0.40 from pre-freeze values and a second flush recovery. We introduced a pixel-based method to evaluate freeze vulnerability, establishing a strong correlation (R values 0.78 to 0.82) between the onset of the first flush (NDVI > 0.50) and the accumulation of 100 growing degree days (GDD). These methods support the potential for retrospective assessments, proactive forest monitoring, and forecasting future risks.

54 ENVIRONMENTAL SCIENCES↗

Calculating the Effects of Solids Input and Removal as a Temperature Control in the Advanced Scale Up Reactor Experiment (ASURE) Facility at NETL Using Aspen

The Advanced Scale Up Reactor Experiment (ASURE) facility at NETL is being designed to be a fuel-flexible multi-purpose reactor that can be used for pyrolysis/gasification or evaluation of other high pressure “circulating fluidized bed” (CFB) chemical processes. The initial system design calculations for pyrolysis/gasification are presented in this work showing the expected performance of the ASURE facility when used as a biomass conversion reactor. Several other areas of application include gasification of any carbonaceous fuel including biomass, coal, plastics, and other waste materials. The reactor can therefore be used to produce SYNGAS of various compositions and hydrogen as well as other high value chemicals resulting from a typical tuned gasification process. This paper discusses an ASPEN model of the facility, focusing on the riser of the CFB reactor and the solids recirculation loop. The ASPEN model divides the riser into two sections. A bottom section which receives ash, char and sand which have been recirculated from a return loop. In this section an inert fluidization gas, (N2 or CO2), is introduced which acts as the primary mover of the solids through the system. The bottom section is equipped with a restricted air feed so that the recirculated char can be partially oxidized. This oxidation process along with the inventory of recirculating sand are used to effectively control the temperature in the following two chemical conversion sections of the reactor which are the pyrolysis zone followed by a tar cracking zone. Fresh fuel is added to the pyrolysis zone and undergoes drying and devolatilization. The products ash, char, volatile matter, and water vapor exit the pyrolysis zone and enter the reaction block for tar cracking. Steam and CO2 gasification reactions will be incorporated into the tar cracking zone, however at the design operating temperature, conversion from these reactions is expected to be essentially zero. The unit when completed in 2026 will test mixtures of biomass, plastics, and waste coal. This paper presents the basic ASPEN engineering design model for this project and provides preliminary sensitivity studies to determine how the various parts of the reactor will perform.

ASSURE↗

Remote sensing of cytotype and its consequences for canopy damage in quaking aspen

Abstract Mapping geographic mosaics of genetic variation and their consequences via genotype x environment interactions at large extents and high resolution has been limited by the scalability of DNA sequencing. Here, we address this challenge for cytotype (chromosome copy number) variation in quaking aspen, a drought‐impacted foundation tree species. We integrate airborne imaging spectroscopy data with ground‐based DNA sequencing data and canopy damage data in 391 km 2 of southwestern Colorado. We show that (1) aspen cover and cytotype can be remotely sensed at 1 m spatial resolution, (2) the geographic mosaic of cytotypes is heterogeneous and interdigitated, (3) triploids have higher leaf nitrogen, canopy water content, and carbon isotope shifts (δ 13 C) than diploids, and (4) canopy damage varies among cytotypes and depends on interactions with topography, canopy height, and trait variables. Triploids are at higher risk in hotter and drier conditions.

Blonder, Benjamin↗

AmeriFlux US-PFk SW1 Aspen-2 CHEESEHEAD 2019

This is the AmeriFlux version of the carbon flux data for the site US-PFk SW1 Aspen-2 CHEESEHEAD 2019. Site Description - This tower (32m, trailer-based, telescoping) is located in the southwestern quadrant of the 10 x 10km study domain. It is located in an aspen forest (canopy height: immediate vicinity - 10m; greater area - 24.4 m).

Desai, Ankur↗

AmeriFlux US-PFL SW2 Aspen-3 CHEESEHEAD 2019

This is the AmeriFlux version of the carbon flux data for the site US-PFL SW2 Aspen-3 CHEESEHEAD 2019. Site Description - This tower (25m Rohn) is located in the southwestern quadrant of the 10 x 10km study domain. It is located in an aspen forest (canopy height: 15 - 19.2 m).

Desai, Ankur↗

AmeriFlux US-PFq SE3 Aspen-4 CHEESEHEAD 2019

This is the AmeriFlux version of the carbon flux data for the site US-PFq SE3 Aspen-4 CHEESEHEAD 2019. Site Description - This tower (32m, trailer-based, telescoping) is located in the southeastern quadrant of the 10 x 10km study domain. It is located in an aspen forest (canopy height: 10 - 14.3 m).

Desai, Ankur↗

AmeriFlux US-PFs SE5 Aspen-5 CHEESEHEAD 2019

This is the AmeriFlux version of the carbon flux data for the site US-PFs SE5 Aspen-5 CHEESEHEAD 2019. Site Description - This tower (12m Rohn) is located in the southeastern quadrant of the 10 x 10km study domain. It is located in an aspen regrowth forest (canopy height: 3.1 - 6 m).

Desai, Ankur↗